Journal
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
Volume 47, Issue 100, Pages 42084-42098Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2021.08.179
Keywords
Canola meal; Low-density polyethylene; Plastic waste; Co-gasification; Supercritical water; Hydrogen
Categories
Funding
- Natural Sciences and Engineering Research Council of Canada
- Canada Research Chairs program
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This study investigates the hydrothermal co-gasification of canola meal and plastic wastes, and the results show that the maximum hydrogen yield can be obtained at optimal temperature and residence time. The gas yield is influenced by the plastic-to-biomass ratio, and synergistic effects between plastic and biomass are observed. The catalytic performance varies in improving hydrogen yield.
Canola meal is a low-value agricultural residue obtained after oil extraction from canola, the utilization of which requires further attention. On the other hand, plastic waste disposal is also another leading issue that creates severe environmental challenges. Supercritical water gasification is considered an environmentally friendly technology to produce hydrogen from plastic residues and organic wastes. This study deals with hydrothermal co-gasification of canola meal and plastic wastes (i.e., low-density polyethylene) while exploring the influence of temperature (375-525 degrees C), residence time (15-60 min) and plastic-to-biomass ratio (0:100, 20:80, 50:50, 80:20 and 100:0) on hydrogen yield. Maximum hydrogen yield (8.1 mmol/g) and total gas yield (17.9 mmol/g) were obtained at optimal temperature and residence time of 525 degrees C and 60 min, respectively. A change in the gas yield with variable plastic-to-biomass ratio showed synergistic effects between both feedstocks. The trend of catalytic performance towards improving hydrogen yield was in the following order: WO(3)eTiO(2) (18.5 mmol/g) > KOH (16.9 mmol/g) > TiO2 (9.5 mmol/g) > ZrO2 (7.8 mmol/g) > WO(3)eZrO(2) (7.4 mmol/g). (c) 2021 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
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