4.7 Article

Synthesis of cobalt loaded double perovskite Sr2TiFeO6-δ (STF) as a stable catalyst for enhanced hydrogen production via methane decomposition

Journal

INTERNATIONAL JOURNAL OF ENERGY RESEARCH
Volume 45, Issue 14, Pages 20073-20088

Publisher

WILEY
DOI: 10.1002/er.7084

Keywords

CNTs; hydrogen production; methane decomposition; perovskite

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In this study, cobalt loaded STF double perovskite was synthesized using a modified nitrate combustion method for methane decomposition. 5% Co/STF exhibited high CH4 conversion and H2 yield, showing excellent catalytic activity and stability.
In this study, cobalt (Co) loaded Sr2TiFeO6-delta (STF) double perovskite was synthesized using a modified nitrate combustion method for the application in catalytic decomposition of methane (CH4) for hydrogen (H-2) production in a fixed bed reactor. The physicochemical properties of the catalyst were analyzed using X-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy, N-2 adsorption-desorption, thermogravimetric analysis (TGA), and Fourier transform infrared spectroscopy. The catalyst showed a stable crystalline behavior with a uniform dispersion of Co over STF. The different compositions with varying Co loading were tested for methane decomposition at 850 degrees C and constant flow rate. The 5% Co/STF achieving a maximum CH4 conversion of similar to 95% with an H-2 yield of similar to 49%. Five percentage Co/STF showed excellent catalytic activity and stability for 46.5 hours time on stream without any indication of performance degradation. The spent catalyst was also analyzed using XRD, SEM, and TGA. The carbon deposited is shaped as carbon nanotubes that are a byproduct and also assist in metal exsolution in high-temperature processes. The use of STF shows the excellent potential showed by perovskites, which are stable in reducing environments, as support materials for methane decomposition.

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