Journal
INTERNATIONAL JOURNAL OF APPLIED CERAMIC TECHNOLOGY
Volume 19, Issue 1, Pages 358-366Publisher
WILEY
DOI: 10.1111/ijac.13896
Keywords
ceramic engineering; dielectric materials; properties; ferromagnetism; ferromagnetic materials; multiferroics; piezoelectric materials; properties
Categories
Funding
- Ministry of Science and Technology, Taiwan [108-2221-E-006-137, 109-2221-E-006-121]
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The sintered CFO-KNN composites showed higher relative density when the volume fraction of KNN reached 50% or more. The highest relative density of 94% was obtained with the composites of 80 vol% KNN. Transmission electron microscopy did not observe any secondary phase at the interface between CFO and KNN grains. However, elemental analyses showed traces of interdiffusion of ions within the solubility limit of both lattices without segregation of other phases.
CoFe2O4-K0.5Na0.5NbO3 (CFO-KNN) composites were sintered in air at 1100 degrees C for 2 h. The relative density of sintered CFO-KNN varied with the KNN/CFO ratio and when the volume fraction of KNN reached 50% or more, the sintered composites had a relative density higher than both of the components (i.e., individually sintered KNN and CFO). The highest relative density (94%) was obtained with the composites of 80 vol% KNN. Transmission electron microscopy did not observe any secondary phase at the interface between CFO and KNN grains. However, elemental analyses showed traces of interdiffusion of Na, K, Co, and Fe ions, which were within the solubility limit of both lattices so that no segregation of other phase occurred. Nevertheless, the interdiffusion altered grain growth kinetics for both phases, resulting in the changes in grain sizes for both KNN and CFO in the composites. The composites of higher CFO content showed lower piezoelectric d(33) due to a higher DC conductivity that resulted in an incomplete poling of samples. The attainable magnetoelectric voltage coefficient was 3.6 mV cm(-1) Oe(-1), which was measured with the composites of 50 vol% KNN.
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