Journal
INORGANIC CHEMISTRY
Volume 60, Issue 12, Pages 8432-8436Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.1c00866
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Funding
- National Natural Science Foundation of China [21971144, 21702228]
- Key R&D Program of Shandong Province [2019GGX102032]
- Natural Science Foundation of Shandong Province [ZR2019ZD46]
- Qilu Youth Scholar Funding of Shandong University [11190088963021]
- Multidisciplinary Research and Innovation Team of Young Scholars of Shandong University [2020QNQT007]
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Researchers have developed a facile route to synthesize B = C double-bonded systems, obtaining corresponding compounds through experiments and further analyzing their electronic structures through theoretical calculations and comparisons.
A facile route to synthesis of B = C double-bonded systems has been developed. Specifically, both dibromofluorenylborane (FluH-BBr2) and a 1,1-dibromo-2,2-difluorenyldiborane/dimethyl sulfide adduct [(FluH)(2)B-BBr2(SMe2)] could be smoothly dehydrobrominated and subsequently coordinated by N-heterocyclic carbenes (NHCs) with formation of the respective alkylideneborane 1 and diborabutadiene 3. The electronic structures of 1 and 3 are interrogated and compared with those of base-free counterparts through density functional theory calculations.
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