Journal
FUEL
Volume 296, Issue -, Pages -Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.fuel.2021.120648
Keywords
NO reduction; Biomass char; Coal char; XPS; Raman spectroscopy
Categories
Funding
- National Key R&D Program of China [2017YFB0602002]
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Under simulated flue gas conditions, different chars showed varying reactivity towards NO reduction, with acid-soaking treatment enhancing char structures. Increased residence time led to higher graphitization degree of chars, and transformations in nitrogen species were observed.
Under simulated flue gas conditions, the effect of the residence time of different chars on the evolution of physiochemical structures during the NO reduction process was evaluated. The experimental data proved that the acid-soaking treatment contributed to the development of char structures. Both biomass chars and H-form chars showed better reactivity on NO reduction, which may be related to smaller average pore diameters, larger BET surface areas and larger pore volumes. The increasing of residence time increased the graphitization degree of all chars, and main reductions of structural defects were from within and between carbon graphene layers. Besides, with the residence time increasing, N-6 and N-5 of R-form Shenmu chars were transformed into N-Q and N-X, while N-X and N-Q (and some N-5) of R-form and H-form sawdust chars were transformed into N-6, which is related to the oxidation or reduction reaction for different chars.
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