4.7 Article

Fabrication of Ti3C2@MoO3 nanocomposite as an electrode material for highly efficient and durable water splitting system

Journal

FUEL
Volume 299, Issue -, Pages -

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.fuel.2021.120928

Keywords

Ti3C2 Mxene; MoO3 nanobelts; Electrocatalyst; Oxygen Evolution Reaction (OER); Hydrogen Evolution Reaction (HER)

Funding

  1. SNS [HEC/R&D/PAKUS/2017/783]
  2. HEC/USAID [HEC/R&D/PAKUS/2017/783]

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In this study, a Ti3C2@MoO3 nanocomposite was synthesized by a hydrothermal method with improved electrocatalytic activity and stability for overall water splitting. The combination of Ti3C2 nanosheets and MoO3 nanobelts in the composite exhibited enhanced HER and OER performance at a low overpotential, showing promise for the development of efficient and durable electrocatalytic systems for water splitting.
Electrocatalytic water splitting is an environmentally benign technique for hydrogen (H-2) and oxygen (O-2) production. Here, synthesis of Ti3C2@MoO3 nanocomposite by hydrothermal method with improved electrocatalytic activity and stability for overall water splitting is reported. In Ti3C2@MoO3 nanocomposite, Ti3C2 acts as a conductive material to facilitate rapid electron transfer whereas; MoO3 provides long-term stability and prevents Ti3C2 nanosheets from restacking. These combined properties of Ti3C2 nanosheets and MoO3 nanobelts exhibited improved HER and OER performance at a low overpotential of 91 mV and 190 mV at a current density of 10 mAcm(-2) with long term durability for 50 h. The strong electronic coupling effect between Ti3C2 MXene and MoO3 nanobelts can accelerate HER/OER kinetics. This study opens new avenues for developing efficient and durable electrocatalytic systems for water splitting.

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