Journal
FOOD CHEMISTRY
Volume 347, Issue -, Pages -Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.foodchem.2021.129075
Keywords
Magnetic covalent organic framework; Room-temperature synthesis; Trace benzoylurea insecticide residue; Tea beverage
Funding
- National Key R&D Program of China [2018YFC1602300]
- National Natural Science Foundation of China [22076086, 21777089]
- Key Research and Development Program of Shandong Province [2019GSF111016]
- Shandong Province Taishan Scholar Program [ts201712063, ts20190948]
- Innovation Project of Science Education Industry [KJC013]
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A novel magnetic covalent organic framework was synthesized and demonstrated to exhibit high adsorption performance towards benzoylurea insecticides. The adsorption mechanism was explained by quantum chemistry calculations, further validating the practical application of this method in tea beverage samples.
A novel magnetic covalent organic framework (NH2-Fe3O4@COF) was prepared using a simple roomtemperature synthesis in this study. These magnetic particles exhibited high adsorption performance with short adsorption time (10 min) for six benzoylurea insecticides (BUs) as magnetic solid-phase extraction (MSPE) adsorbents. Quantum chemistry calculation demonstrated that adsorption mechanism was primarily attributed to strong halogen bonds between electronegative O atoms of COF and electropositive F atoms of BUs as well as potential hydrophobic effect. Wide linearities (10-1000 ng.L-1) and low limits of detection (0.06-1.65 ng.L-1) for six analytes were obtained via liquid chromatography-tandem mass spectrometry. Applicability of the proposed method was further evaluated by analyzing four kinds of original tea beverages. Recoveries of six BUs in spiked samples ranged from 80.1% to 108.4%.
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