Journal
FOOD AND BIOPRODUCTS PROCESSING
Volume 129, Issue -, Pages 1-9Publisher
ELSEVIER
DOI: 10.1016/j.fbp.2021.06.006
Keywords
Succinic acid; Whey; Nanofiltration; Reverse osmosis
Funding
- Scientific and Technological Research Council of Turkey (TuBITAK) [115Y824]
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In this study, two alternative systems for the recovery of bio-based succinic acid were demonstrated, with efficiency achieved through chromatographic separation and membrane separation technologies. High purity succinic acid crystals were successfully obtained, setting a stage for efficient downstream purification of succinic acid in further research.
Succinic acid is a key platform chemical for production of various products such as biodegradable polymers, pharmaceuticals, fine chemicals and foods. In the present study, bio-based succinic acid was recovered through two processes. Process I consisted of chro-matographic separation with anionic exchange resin followed by direct crystallization, whereas process II sequentially consisted of cationic exchanger, activated carbon, NF/RO membrane, vacuum distillation, and crystallization. The highest chromatographic separa-tion efficiency for succinic acid by Amberlite IRA900 Cl column was calculated as 69.3% at flow rate of 0.42 BV/h. Rejection of succinic aid (SA), lactic acid (LA), formic acid (FA) and acetic acid (AC) by NF90 membrane was 53.1, 51.8, 46.6 and 39.8%, respectively at pH less than 2. However, at pH 6.8 the respective rejections increased to 96.8, 90.6, 71.3 and 70.5%. Double pass with BW30 or HP reverse osmosis membranes achieved retention of SA, LA, FA and AC of 95.9%, 95.8%, 65.4% and 46.9%, respectively. Analysis of generated SA crystals by X-ray diffraction technique (XRD) and Fourier transform infrared (FTIR) showed the crys-tallinity of recovered SA as conformable to standard grade crytsals. The purity of generated succinic acid crystals was recorded as 98.5% and 96.7% for process I and process II, respec-tively. The calculated succinic acid yield was 78% for process I and 65% for process II. Herein, we demonstrated two alternative systems for bio-based succinic acid recovery, which will set a stage for research in efficient downstream purification of SA. (c) 2021 Institution of Chemical Engineers. Published by Elsevier B.V. All rights reserved.
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