Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2021, Issue 44, Pages 6006-6014Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.202101084
Keywords
Asymmetric; C-H Activation; Organosilanes; Si-stereogenic; Silylation
Categories
Funding
- Shanghai Institute of Organic Chemistry, State Key Laboratory of Organometallic Chemistry, > Shanghai Rising-Star Program [20QA1411400]
- National Natural Science Foundation of China [21821002, 22171277, 22101291]
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This Minireview summarizes the recent advances in the construction of Si-stereogenic silanes through the transition-metal-catalyzed C-H activation approach, showcasing their significant synthetic value.
The asymmetric synthesis of Si-stereogenic silanes has attracted great attention due to the increasing values of Si-containing functional molecules in synthetic chemistry, medicinal chemistry, and material chemistry. Merging organosilicon chemistry with transition-metal-catalyzed C-H approach has led to rich sets of new reactions holding great synthetic values. This Minireview aims to summarize the advances in the construction of Si-stereogenic silanes through the transition-metal-catalyzed C-H activation approach.
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