Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2021, Issue 41, Pages 5571-5584Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.202100944
Keywords
Fluoroalkylthiolation; Fluoroalkylselenolation; Fluorine; Sulfur; Selenium
Categories
Funding
- region Rhone Alpes
- CNRS
- ICBMS [UMR 5246]
- ICL (Institut de Chimie de Lyon)
- French Fluorine Network
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Reagent design plays a crucial role in modern organofluorine chemistry, with a focus on introducing fluoroalkylthio or seleno groups efficiently and selectively. Among them, versatile fluoroalkyl thiosulfonates and selenosulfonates have been at the forefront of recent developments, showing rich chemical reactivity and wide applicability in various studies.
Reagent design is at the cornerstone of modern organofluorine chemistry. The past decades have seen the emergence of diverse families of reagents with the aim of introducing fluoroalkylthio or seleno groups in an efficient and selective way. Among them, highly versatile fluoroalkyl thiosulfonates and selenosulfonates are in the foreground of the recent developments. Their applicability is discussed in detail in this Minireview, with a specific focus on the reactivity and activation modes.
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