Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2021, Issue 39, Pages 5403-5406Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.202101042
Keywords
Green chemistry; Michael addition; Minimalistic peptides; Organocatalysis; Self-assembly
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Funding
- Foundation Fondazione Cassa di Risparmio di Modena - FCRM
- Royal Society of Chemistry Research Fund [RF19-5583, R19-3106]
- MUR [E51I17000660005]
- Universita degli Studi dell'Aquila within the CRUI-CARE Agreement
- Department of Life Sciences [E51I17000660005]
- UniMORE [E51I17000660005]
- [PON - AIM1842894]
- [CUP E18D19000560001]
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Self-assembling minimalistic peptides with an organocatalytic moiety were designed and controlled by external intervention to accelerate activation. The accelerated catalysis was demonstrated in a Michael benchmark reaction.
Self-assembling minimalistic peptides embedded with an organocatalytic moiety were designed. By controlling the formation of fibrils via external intervention, it was shown that the activation is accelerated when the organocatalyst is in its supramolecular state. The effect of the accelerated catalysis was demonstrated in a Michael benchmark reaction.
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