Related references
Note: Only part of the references are listed.Tuning the reactivity of alkoxyl radicals from 1,5-hydrogen atom transfer to 1,2-silyl transfer
Zhaoliang Yang et al.
NATURE COMMUNICATIONS (2021)
A Simple Protocol from Benzalacetones to 1,1,1-Trifluoro-2,5-diketones and 2-(Trifluoromethyl)furans by Reductive Trifluoroacetylation
Tianyuan Zhang et al.
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY (2020)
Direct transfer of tri- and di-fluoroethanol units enabled by radical activation of organosilicon reagents
Xiang Chen et al.
NATURE COMMUNICATIONS (2020)
Synergistic Activation of Amides and Hydrocarbons for Direct C(sp3)-H Acylation Enabled by Metallaphotoredox Catalysis
Geun Seok Lee et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)
Fluoroalkylation of Allylic Alcohols with Concomitant (Hetero)aryl Migration: Access to Fluoroalkylated Ketones and Evaluation of Antifungal Action againstMagnaporthe grisea
Yanhu Zhang et al.
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY (2020)
Radical-Mediated Distal Ipso-Migration of O/S-Containing Heteroaryls and DFT Studies for Migratory Aptitude
Huihui Zhang et al.
ORGANIC LETTERS (2020)
Metal-Free Chemoselective Reaction of Sulfoxonium Ylides and Thiosulfonates: Diverse Synthesis of 1,4-Diketones, Aryl Sulfursulfoxonium Ylides, and β-Keto Thiosulfones Derivatives
Fei Wang et al.
ORGANIC LETTERS (2020)
Iron-catalyzed acylation-functionalization of unactivated alkenes with aldehydes
Tian Tian et al.
CHEMICAL COMMUNICATIONS (2020)
Electrochemical Radical Selenylation/1,2-Carbon Migration and Dowd Beckwith-Type Ring-Expansion Sequences of Alkenylcyclobutanols
Yeon Joo Kim et al.
ORGANIC LETTERS (2019)
CF2H, a Functional Group-Dependent Hydrogen-Bond Donor: Is It a More or Less Lipophilic Bioisostere of OH, SH, and CH3?
Yossi Zafrani et al.
JOURNAL OF MEDICINAL CHEMISTRY (2019)
Electrochemical Oxidative Aryl(alkyl)trifluoromethylation of Allyl Alcohols via 1,2-Migration
Zhipeng Guan et al.
ORGANIC LETTERS (2019)
Photocatalyzed Metal-Free Alkylheteroarylation of Unactivated Olefins via Direct Acidic C(sp3)-H Bond Activation
Jie Fang et al.
ORGANIC LETTERS (2019)
Visible-Light-Promoted Cascade Radical Cyclization: Synthesis of 1,4-Diketones Containing Chroman-4-One Skeletons
Xiang-Kui He et al.
CHEMISTRY-AN ASIAN JOURNAL (2019)
Photocatalytic Radical Aroylation of Unactivated Alkenes: Pathway to β-Functionalized 1,4-, 1,6-, and 1,7-Diketones
Satavisha Sarkar et al.
ACS CATALYSIS (2019)
4-Ethoxy-1,1,1-trifluoro-3-buten-2-one (ETFBO), a Versatile Precursor for Trifluoromethyl-Substituted Heteroarenes - a Short Synthesis of Celebrex (R) (Celecoxib)
Heiko Sommer et al.
SYNLETT (2018)
Recent Advances in the Synthesis of beta-Functionalized Ketones by Radical-Mediated 1,2-Rearrangement of Allylic Alcohols
Wei-Zhi Weng et al.
CHEMISTRY-A EUROPEAN JOURNAL (2018)
Carbonyl-Oxygen-Assisted KOMe-Mediated Formal Hydration of 4-Alkynones: Complete Regioselectivity in the One-Pot Synthesis of 1,4-Diketones under Mild Conditions
Xue-Ting Bai et al.
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY (2018)
Synthesis of Trifluoroacetyl-Substituted Cyclopropanes Using Onium Ylides
Michael Winter et al.
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY (2018)
Facile synthesis of 1,4-diketones via three-component reactions of alpha-ketoaldehyde, 1,3-dicarbonyl compound, and a nucleophile in water
Jian Yang et al.
GREEN CHEMISTRY (2018)
Fluorine and Fluorinated Motifs in the Design and Application of Bioisosteres for Drug Design
Nicholas A. Meanwell
JOURNAL OF MEDICINAL CHEMISTRY (2018)
Eosin Y-catalyzed, visible-light-promoted carbophosphinylation of allylic alcohols via a radical neophyl rearrangement
Yao Yin et al.
ORGANIC & BIOMOLECULAR CHEMISTRY (2018)
Synthesis of 1,4-Diketones via Titanium-Mediated Reductive Homocoupling of -Haloketones
Nathan N. Le et al.
SYNLETT (2018)
Difluoromethyl Bioisostere: Examining the Lipophilic Hydrogen Bond Donor Concept
Yossi Zafrani et al.
JOURNAL OF MEDICINAL CHEMISTRY (2017)
Nitroalkenes as Latent 1,2-Biselectrophiles - A Multicatalytic Approach for the Synthesis of 1,4-Diketones and Their Application in a Four-Step One-Pot Reaction to Polysubstituted Pyrroles
Patrick J. W. Fuchs et al.
JOURNAL OF ORGANIC CHEMISTRY (2017)
CF2H, a Hydrogen Bond Donor
Chanan D. Sessler et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)
Oxidative [1,2]-Brook Rearrangements Exploiting Single-Electron Transfer: Photoredox-Catalyzed Alkylations and Arylations
Yifan Deng et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)
Chemo- and Regioselective Distal Heteroaryl ipso-Migration: A General Protocol for Heteroarylation of Unactivated Alkenes
Zhen Wu et al.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)
Iron-Promoted Difunctionalization of Alkenes by Phenylselenylation/1,2-Aryl Migration
Ping Wu et al.
ORGANIC LETTERS (2017)
Copper-Catalyzed C(sp3)-H/C(sp3)-H Cross-Dehydrogenative Coupling with Internal Oxidants: Synthesis of 2-Trifluoromethyl-Substituted Dihydropyrrol-2-ols
Chuanle Zhu et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)
Recent Advances in Radical C-H Activation/Radical Cross-Coupling
Hong Yi et al.
CHEMICAL REVIEWS (2017)
2-Oxindole Acts as a Synthon of 2-Aminobenzoyl Anion in the K2CO3-Catalyzed Reaction with Enones: Preparation of 1,4-Diketones Bearing an Amino Group and Their Further Transformations
Chun-Bao Miao et al.
JOURNAL OF ORGANIC CHEMISTRY (2016)
Synthesis of 1,4-Diketones from -Oxo Esters and Enol Acetates by Cerium-Catalyzed Oxidative Umpolung Reaction
Irina Geibel et al.
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY (2016)
Development of a Palladium-Catalyzed Carbonylative Coupling Strategy to 1,4-Diketones
Hongfei Yin et al.
ACS CATALYSIS (2016)
1,4-Diketones from Cross-Conjugated Dienones: Potassium Permanganate-Interrupted Nazarov Reaction
Yonghoon Kwon et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2015)
Palladium-catalyzed cross-coupling of α-bromocarbonyls and allylic alcohols for the synthesis of α-aryl dicarbonyl compounds
Yang Yu et al.
CHEMICAL SCIENCE (2015)
Synthetic Methods for Compounds Having CF3-S Units on Carbon by Trifluoromethylation, Trifluoromethylthiolation, Triflylation, and Related Reactions
Xiu-Hua Xu et al.
CHEMICAL REVIEWS (2015)
A radical thia-Brook rearrangement
Beatrice Quiclet-Sire et al.
CHEMICAL COMMUNICATIONS (2014)
Visible-Light-Induced C - S Bond Activation: Facile Access to 1,4-Diketones from β-Ketosulfones
Jun Xuan et al.
CHEMISTRY-A EUROPEAN JOURNAL (2014)
Copper-Catalyzed Tandem Trifluoromethylation/Semipinacol Rearrangement of Allylic Alcohols
Zhi-Min Chen et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2013)
Copper-Catalyzed Trifluoromethylation-Initiated Radical 1,2-Aryl Migration in ,-Diaryl Allylic Alcohols
Xiaowu Liu et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2013)
Introduction of Fluorine and Fluorine-Containing Functional Groups
Theresa Liang et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2013)
Dehydrogenation of Perfluoroalkyl Ketones by Using a Recyclable Oxoammonium Salt
Trevor A. Hamlin et al.
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY (2013)
Asymmetric Construction of Stereogenic Carbon Centers Featuring a Trifluoromethyl Group from Prochiral Trifluoromethylated Substrates
Jing Nie et al.
CHEMICAL REVIEWS (2011)
Titanium-Mediated Synthesis of 1,4-Diketones from Grignard Reagents and Acyl Cyanohydrins
Paul Setzer et al.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2010)
Fluorine in health care Organofluorine containing blockbuster drugs
David O'Hagan
JOURNAL OF FLUORINE CHEMISTRY (2010)
Selective difluoromethylation and monofluoromethylation reactions
Jinbo Hu et al.
CHEMICAL COMMUNICATIONS (2009)
Fluorine in medicinal chemistry
Sophie Purser et al.
CHEMICAL SOCIETY REVIEWS (2008)
Aromatization via a dibromination-double dehydrobromination sequence:: A facile and convenient synthetic route to 2,6-bis(trifluoroacetyl)phenols
Dmitri V. Sevenard et al.
SYNTHESIS-STUTTGART (2008)
Trifluoromethyl group as a pharmacophore:: Effect of replacing a CF3 group on binding and agonist activity of a glucocorticoid receptor ligand
R Betageri et al.
BIOORGANIC & MEDICINAL CHEMISTRY LETTERS (2005)
Trifluoromethyl group: an effective xenobiotic function for peptide backbone modification
M Zanda
NEW JOURNAL OF CHEMISTRY (2004)
The Brook rearrangement in tandem bond formation strategies
WH Moser
TETRAHEDRON (2001)
On the radical brook rearrangement.: Reactivity of α-silyl alcohols, α-silyl alcohol nitrite esters, and β-haloacylsilanes under radical-forming conditions
MD Paredes et al.
JOURNAL OF ORGANIC CHEMISTRY (2000)
Share Paper
