Adsorption of Hg(II) in solution by mercaptofunctionalized palygorskite

In the past 10 years, the treatment and restoration of soil and water bodies contaminated by mercury and other heavy metals have received unprecedented attention and support from China's environmental protection authorities. The search for low-cost and high-efficiency adsorbents has become one of the research hotspots in this field. In this paper, a simple and environment-friendly method was used to graft 3-mercaptopropyl trimethoxysilane on the surface of palygorskite. The synthesized mercaptofunctionalized palygorskite (M-PAL) was characterized by XRD, FT-IR, BET and SEM-EDS, respectively, and its adsorption conditions, adsorption models and thermodynamic parameters for Hg2+ were systematically investigated. The experimental results indicated that the saturated adsorption capacity of Hg2+ on the M-PAL could reach 203.4 mg center dot g(-1), within 120 min at pH 4 and 298 K. By analyzing the experimental data of adsorption kinetics and thermodynamics, it was found that the adsorption process of Hg2+ conformed to the pseudo-second-order kinetic model, which belonged to chemical adsorption of the rate-controlled step; the Langmuir model better described the adsorption isotherm. The thermodynamic parameters obtained (Delta H=29.95 kJ center dot mol(-1), Delta S=103.09 J center dot mol(-1)center dot K-1 and Delta G<0) show that the whole process is a spontaneous endothermic process. When the concentration of Na+, K+, Ca2+, Mg2+, Cl-, NO3-, H2C2O4 and C6H8O7 was 200 times that of Hg2+, although these organic acids had a slightly greater effect on the adsorption of Hg2+ on mercaptofunctionalized palygorskite than inorganic ions, the adsorption capacity remained above 185 mg center dot g(-1). The adsorption products could be still stable in simulated acid rain with pH 3, 4, 5, 6, 7 and oxalic acid solution with concentration of 1, 2, 3, 4 and 5 mmol center dot L-1, and the desorption rates were about 3%. Through XPS analysis, the specific coordination of Hg2+ with the S atom on the surface of M-PAL was confirmed.

Automated summary

In the past decade, the treatment and restoration of soil and water contaminated by mercury and other heavy metals have been a major focus of China's environmental protection authorities. The search for low-cost and high-efficiency adsorbents has become a research hotspot, leading to the development of mercaptofunctionalized palygorskite as an effective adsorbent for Hg2+. The experimental results demonstrated a high adsorption capacity and favorable thermodynamic parameters for Hg2+, with the adsorption process following a pseudo-second-order kinetics model and the Langmuir model well describing the adsorption isotherm.