Journal
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
Volume 29, Issue 8, Pages 11219-11231Publisher
SPRINGER HEIDELBERG
DOI: 10.1007/s11356-021-16401-0
Keywords
MICP; MISP; Sand column; Strength; Alkali-activated mortar
Categories
Funding
- Opening Funds of Jiangsu Key Laboratory of Construction Materials of Southeast University [CM2018-02]
- National Natural Science Foundation of China [51702238]
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Microbial induced mineral precipitation technology can modify and improve construction materials, reduce initial porosity, increase strength, and decrease permeability coefficient. The process includes MICP and MISP, which use urease-producing bacteria to create carbonate or struvite precipitates, analyzed by EDS and XRD, with morphology observed through SEM.
The microbial induced mineral precipitation can be used to modify and improve the performance of construction materials and can partially replace ordinary Portland cement. Microbially induced carbonate precipitation (MICP) mainly uses the urease secreted during the growth of urease-producing bacteria (UPB) to hydrolyze urea produce CO32- and reacts with Ca2+ to form CaCO3. Microbially induced struvite precipitation (MISP) mainly uses the urease to decompose urea to produce NH4+. In the presence of hydrogen phosphate and magnesium ions, the struvite can be precipitated. The elemental composition and chemical composition of the precipitates produced by the MICP and MISP processes are analyzed by energy dispersive X-ray spectroscopy (EDS) and powder X-ray diffraction analysis (XRD). The morphology of the precipitates can be observed by scanning electron microscope (SEM). Compared with the initial porosity, the MICP method can reduce the initial porosity of the sand column by 2.98% within 90 min. However, the MISP is only 1.45%. The permeability coefficient of the sand column can be effectively reduced in the MICP process. The total content of cementitious materials is 27.71g and 13.16g in MICP- and MISP-cemented sand columns, respectively. The MICP technology can improve the strength of alkali-activated mortars under different pH values of the UPB solution.
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