4.8 Article

Room-to-Room Variability of Airborne Polychlorinated Biphenyls in Schools and the Application of Air Sampling for Targeted Source Evaluation

Journal

ENVIRONMENTAL SCIENCE & TECHNOLOGY
Volume 55, Issue 14, Pages 9460-9468

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.est.0c08149

Keywords

polychlorinated biphenyls; atmospheric chemistry; gas chromatography mass spectrometry; positive matrix factorization; principal component analysis; Aroclor; non-Aroclor

Funding

  1. National Institute of Environmental Health Sciences of the National Institutes of Health [P42ES013661]
  2. National Science Foundation (NSF) through the NSF Division of Graduate Education [1633098]
  3. Division Of Graduate Education
  4. Direct For Education and Human Resources [1633098] Funding Source: National Science Foundation

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The study reveals that airborne PCB concentrations in schools are higher indoors than outdoors, originating from different sources. There are variations in concentration and congener profiles among different rooms, with higher levels found in older wing of the building. The congener distributions suggest both historical and modern sources of PCBs.
Airborne polychlorinated biphenyl (PCB) concentrations are higher indoors than outdoors due to their historical use in building materials and their presence in modern paints and surface treatments. For some populations, including school children, PCB levels indoors result in inhalation exposures that may be greater than or equivalent to exposure through diet. In a school, PCB exposure may come from multiple sources. We hypothesized that there are both Aroclor and non-Aroclor sources within a single school and that PCB concentration and congener profiles differ among rooms within a single building. To evaluate this hypothesis and to identify potential localized sources, we measured airborne PCBs in nine rooms in a school. We found that schoolroom concentrations exceed outdoor air concentrations. Schoolroom concentrations and congener profiles also varied from one room to another. The concentrations were highest in the math room (35.75 ng M-3 +/- 8.08) and lowest in the practice gym (1.54 ng M-3 +/- 0.35). Rooms in the oldest wing of the building, originally constructed between 1920 and 1970, had the highest concentrations. The congener distribution patterns indicate historic use of Aroclor 1254 as well as modern sources of non-Aroclor congeners associated with paint pigments and surface coatings. Our findings suggest this noninvasive source identification method presents an opportunity for targeted source testing for more cost-effective prioritization of materials remediation in schools.

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