Journal
ENVIRONMENTAL POLLUTION
Volume 285, Issue -, Pages -Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.envpol.2021.117398
Keywords
Adsorption; Plastics particles; Tetracycline; Surface acidity; Surface complexes
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Funding
- Ministry of Science and Technology (MOST), Taiwan [108-2113-M-110-004, 109-2222-E-992-002]
- US NSF IOA [1632899]
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The study investigated the adsorption of tetracycline on high-density polyethylene particles and found that pH controls the surface charge of PE particles. Tetracycline adsorption onto PE particles was rapid, following the pseudo-second-order rate law. In addition to specific chemical interactions, polar forces played a significant role in controlling TC adsorption onto PE particles.
The presence of ultrafine plastics particles and its potential to concentrate and transport organic contaminants in aquatic environments have become a major concern in recent years. Specifically, the uptake of hazardous chemicals by plastics particles may affect the distribution and bioavailability of the chemicals. In this study, the adsorption of tetracycline (TC), an antibiotic frequently found in aquatic environments, on high-density polyethylene (PE) particles with the average size of 45 mu m, was investigated. The PE particles were characterized for surface acidity for the first time. Results showed that pH controls the surface charge of PE particles. TC adsorption onto PE particles was rapid as expected following the pseudo-second-order rate law (r(2) > 0.99). Polar forces in addition to specific chemical interactions, such as hydrogen bonding and hydrophophilicity controlled TC adsorption onto PE particles. Parameters, including pH, dissolved organic matter, ionic strength, major cations and anions affected TC adsorption onto PE micro-particles. Results indicated that PE particles can function as a carrier of antibiotics in the aquatic environment, which potentially imposes ecosystem and human health risks.
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