4.8 Review

Electrochemical recovery and high value-added reutilization of heavy metal ions from wastewater: Recent advances and future trends

Journal

ENVIRONMENT INTERNATIONAL
Volume 152, Issue -, Pages -

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.envint.2021.106512

Keywords

Heavy metals; Electrochemical; Recovery; Mass transfer; Value-added

Funding

  1. National Science Foundation of China [52060018, 51808279]
  2. National Key Research and Development Program of China [2018YFC0406400, 2019YFC1907900]
  3. Key Science and Technology Projects of Inner Mongolia Autonomous Region [2019ZD001]
  4. Key Project of Research and Development Plan of Jiangxi Province [20201BBE51007]
  5. Fostering Project of National Science and Technology Awards of Jiangxi Province [20192AEI91001]

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This review discusses recent advances in electrochemical metal recovery techniques, aiming to target recycling heavy metal resources with minimize energy consumption, boost recovery efficiency, and realize commercial application.
Wastewater treatment for heavy metals is currently transitioning from pollution remediation towards resource recovery. As a controllable and environment-friendly method, electrochemical technologies have recently gained significant attention. However, there is a lack of systematic and goal oriented summarize of electrochemical metal recovery techniques, which has inhibited the optimized application of these methods. This review aims at recent advances in electrochemical metal recovery techniques, by comparing different electrochemical recovery methods, attempts to target recycling heavy metal resources with minimize energy consumption, boost recovery efficiency and realize the commercial application. In this review, different electrochemical recovery methods (including E-adsorption recovery, E-oxidation recovery, E-reduction recovery, and E-precipitation recovery) for recovering heavy metals are introduced, followed an analysis of their corresponding mechanisms, influencing factors, and recovery efficiencies. In addition, the mass transfer efficiency can be promoted further through optimizing electrodes and reactors, and multiple technologies (photo-electrochemical and sono-electrochemical) could to be used synergistically improve recovery efficiencies. Finally, the most promising directions for electrochemical recovery of heavy metals are discussed along with the challenges and future opportunities of electrochemical technology in recycling heavy metals from wastewater.

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