Journal
ELECTROCHIMICA ACTA
Volume 391, Issue -, Pages -Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2021.138898
Keywords
Electropolymerization; Polycarbazole; Polycarbazole-sulfur cathode; Lithium-sulfur battery
Categories
Funding
- Swinburne University of Technology
- CSIRO, Australia
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The potential use of electrochemically polymerized polycarbazole as an additive in lithium-sulfur battery cathodes has been investigated, showing promising initial discharge capacity and cycling performance through optimization of the electropolymerization process and formulation.
The potential use of electrochemically polymerized polycarbazole as an additive in lithium-sulfur battery cathodes has been investigated. Optimization of the polymer properties considered solvent, electrolyte and current-time profile during electropolymerization. It was found that electrodeposition from LiClO4-acetonitrile electrolyte and constant-potential deposition (at 1.15 V vs Ag/Ag+) gives the highest initial discharge capacity. This is most likely due to an optimum combination of specific surface area and conductivity. To improve the quality of the cathode, a slurry of carbon disulfide and dimethyl formamide was devised to balance the dispersion of carbon black and the solubility of sulfur. In 2032-coin cells, against a lithium anode, a polycarbazole-sulfur (PCBz-S) cathode with 30% sulphur showed the highest initial discharge capacity. A very good coulombic efficiency of around 98% and a capacity retention of over 91% for 50 charge/discharge cycles were obtained for the optimized PCBz-S cathode. Based on the cycling performance, PCBz is a potentially useful additive to mitigate the polysulfide shuttle effect. In addition, the electropolymerized carbazole matches the performance of a commercial polypyrrole that has been widely used as a conductive binder. (C) 2021 Elsevier Ltd. All rights reserved.
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