Journal
CORROSION SCIENCE
Volume 190, Issue -, Pages -Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.corsci.2021.109646
Keywords
Titanium; Corrosion; Anatase; Rutile; Ilmenite; Pressurised water
Funding
- Centre of Excellence of Multifunctional Architectured Materials CEMAM - Investments for the Future programme [ANR10LABX4401]
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The corrosion of titanium alloys in primary water at 300 degrees Celsius resulted in a global weight gain due to oxidation and surface precipitation, with a protective ilmenite layer finally precipitating at the surface of the samples.
The corrosion of titanium alloys in primary water at 300 degrees C led to a global weight gain due to oxidation and surface precipitation, despite some dissolution. A model was proposed, taking into account the weight contribution of each oxide type to the global mass evolution with exposure time. Based on this model, on mass variation and GD-OES results, a corrosion rate ranging between 2 and 6.6 mu m.year-1 at 300 degrees C for all tested materials was estimated. Due to the simultaneous corrosion of the used stainless steel reactors, a protective ilmenite layer finally precipitated at the surface of the samples.
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