Journal
CHINESE JOURNAL OF CHEMICAL ENGINEERING
Volume 47, Issue -, Pages 174-184Publisher
CHEMICAL INDUSTRY PRESS CO LTD
DOI: 10.1016/j.cjche.2021.08.005
Keywords
C- 4 alkylation; Surface; Zeolite; Catalysis; DFT calculation
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Funding
- National Natural Science Foundation of China [21978325, 21776312, 21908186]
- Independent Innovation Foundation of Qingdao [17-1-1-18-jch]
- Fundamental Research Funds for the Central Universities [18CX02014A]
- Fundamental Research Funds for the Central Universities
- Opening Fund of State Key Laboratory of Heavy Oil Processing [SKLOP202003002]
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In this study, the confinement effect on zeolite catalysts for C4 alkylation was investigated using DFT calculations, experiments, and multi-techniques. The results showed that the main active sites for the reaction were located on the internal surface of the catalysts, and the external surface exhibited stronger selectivity for C4 olefin adsorption. The insights from this work provide important references for the design of highly effective zeolite catalysts.
Elucidating the confinement effect harbours tremendous significance for isobutane alkylation with C4 olefin. Herein, the confinement effect over zeolite catalysts was elucidated by combining DFT calculations, experiments (using the novel Beta zeolite exposing only external surfaces (Beta-E) and conventional Beta-I zeolite with both external and internal surfaces) and multi-techniques (e.g., TGA-DTG, HRTEM, SEM and XRD). It is found that the main active sites for C4 alkylation reaction are located on internal surface rather than external surface. On the external surface, the hydride transfer reaction does not occur because the H-shared intermediate cannot be formed without the confinement effect. Moreover, the external surface has stronger selectivity for C4 olefin adsorption than isobutane, leading to enhanced oligomerization reactions. Therefore, the suitable micropore with confinement effect is essential for zeolite-catalyzed C4 alkylation. The atomic-scale insights of this work are of great referential importance to the design of highly effective zeolite catalyst. (c) 2021 The Chemical Industry and Engineering Society of China, and Chemical Industry Press Co., Ltd. All rights reserved.
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