Electrocatalytic Oxygen Evolution Reaction in Acidic Conditions: Recent Progress and Perspectives

The electrochemical oxygen evolution reaction (OER) is an important half-cell reaction in many renewable energy conversion and storage technologies, including electrolyzers, nitrogen fixation, CO2 reduction, metal-air batteries, and regenerative fuel cells. Among them, proton exchange membrane (PEM)-based devices exhibit a series of advantages, such as excellent proton conductivity, high durability, and good mechanical strength, and have attracted global interest as a green energy device for transport and stationary sectors. Nevertheless, with a view to rapid commercialization, it is urgent to develop highly active and acid-stable OER catalysts for PEM-based devices. In this Review, based on the recent advances in theoretical calculation and in situ/operando characterization, the OER mechanism in acidic conditions is first discussed in detail. Subsequently, recent advances in the development of several types of acid-stable OER catalysts, including noble metals, non-noble metals, and even metal-free OER materials, are systematically summarized. Finally, the current key issues and future challenges for materials used as acidic OER catalysis are identified and potential future directions are proposed.

Automated summary

This review discusses the OER mechanism in acidic conditions and summarizes recent advances in the development of several types of acid-stable OER catalysts. Current key issues and future challenges have been identified, along with proposed potential future directions for materials used as acidic OER catalysis.