Journal
CHEMSUSCHEM
Volume 14, Issue 21, Pages 4752-4763Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cssc.202101670
Keywords
co-catalysts; composites; photocatalytic hydrogen evolution; tungsten sulfide; zinc cadmium sulfide
Funding
- Natural Science Foundation of Tianjin [18JCYBJC17700]
- National Natural Science Foundation of China [21406164, 21466035]
- National Key Basic Research and Development Program of China (973 Program) [2014CB239300]
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By using 1T-WS2 as a cocatalyst, a 1T-WS2/Zn0.5Cd0.5S composite with high photocatalytic hydrogen evolution efficiency was successfully constructed in this study. The synergistic effect between 1T-WS2 and Zn0.5Cd0.5S promotes the electron transfer and separation, resulting in enhanced hydrogen evolution rate and external quantum efficiency.
Due to inefficient charge separation and low surface catalytic conversion efficiencies, cocatalysts are required for achieving photocatalytic hydrogen evolution. Being a noble-metal-free cocatalyst, metallic 1T-WS2 with excellent conductivity can function for this reaction. Herein, 1T-WS2/Zn0.5Cd0.5S is constructed via a simple and feasible grinding approach. The composite containing 7.5 % 1T-WS2 in 1T-WS2/Zn0.5Cd0.5S achieves a hydrogen evolution rate of 61.65 mmol g(-1) h(-1) and an external quantum efficiency of 8.04 % at 420 nm, which is 37 times that of bare Zn0.5Cd0.5S (1.67 mmol g(-1) h(-1)). The electrical conductivity of metallic 1T-WS2 reduces the transfer impedance at the interface and thus accelerates the non-radiative energy transfer and electron transport rate. The different Fermi levels of 1T-WS2 and Zn0.5Cd0.5S form a Schottky junction, which promotes the transfer of photogenerated electrons from Zn0.5Cd0.5S to 1T-WS2. More importantly, the close interface contact between 1T-WS2 and Zn0.5Cd0.5S results in strong electron interactions, which is conducive to the spatial separation of photogenerated electrons and holes. This work will further expand the application of 1T-WS2 in the photocatalytic hydrogen evolution process.
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