4.6 Article

Facile one-step synthesis of Ru doped NiCoP nanoparticles as highly efficient electrocatalysts for oxygen evolution reaction

Journal

CHEMISTRY-AN ASIAN JOURNAL
Volume 16, Issue 22, Pages 3630-3635

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.202100810

Keywords

Ru doping; phosphide; pre-catalyst; oxygen evolution reaction; cation vacancy

Funding

  1. National Research Foundation of Korea (NRF) - Korean government (Ministry of Science and ICT (MSIT)) [2019M3E6A1063674, NRF-2021M3I3A1082879]
  2. KIST institutional program [2E31002]
  3. National Research Foundation of Korea [NRF-2020R1A2B5B03002475, NRF-2019R1A6A1A11044070, NRF-2019M3E6A1064709]
  4. INHA UNIVERSITY Research Grant
  5. KBSI project [C123000]
  6. National Research Foundation of Korea [2019M3E6A1064709] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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This study presents a facile synthetic route to NiCoP nanoparticles with Ru dopants, which exhibit high catalytic performance for the oxygen evolution reaction (OER) in alkaline media with low overpotential and high Tafel slope. The Ru dopants induce a higher content of Ni and Co vacancies in NiCoP nanoparticles, leading to more catalytically active sites and improved electrical conductivity after electrochemical activation.
Transition metal phosphides (TMPs) as ever-evolving electrocatalytic materials have attracted increasing attention in water splitting reactions owing to their cost-effective, highly active and stable catalytic properties. This work presents a facile synthetic route to NiCoP nanoparticles with Ru dopants which function as highly efficient electrocatalysts for oxygen evolution reaction (OER) in alkaline media. The Ru dopants induced a high content of Ni and Co vacancies in NiCoP nanoparticles, and the more defective Ru doped NiCoP phase than undoped NiCoP ones led to a greater number of catalytically active sites and improved electrical conductivity after undergoing electrochemical activation. The Ru doped NiCoP catalyst exhibited high OER catalytic performance in alkaline media with a low overpotential of 281 mV at 10 mA cm(-2) and a Tafel slope of 42.7 mV dec(-1).

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