Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 27, Issue 52, Pages 13211-13220Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.202101428
Keywords
MgO-based catalysts; layered double hydroxides; topological transformation; photodriven catalysis; methane coupling reaction
Categories
Funding
- National Natural Science Foundation of China [U1707603, 21625101, 21878008, 21922801, U1507102]
- Beijing Natural Science Foundation [2182047, 2202036]
- Fundamental Research Funds for the Central Universities [XK1802-6]
- Key Laboratory of New Processing Technology for Nonferrous Metal Materials
- Ministry of Education/Guangxi Key Laboratory of Optical and Electronic Materials and Devices [GUTQDJJ2019133, 20KF-3]
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This study demonstrates the conversion of methane to high value-added chemicals with a selectivity of 41.60% using Co-doped MgO-based catalysts. The transformation of layered double hydroxides into catalysts opens up a promising pathway for photodriven methane coupling.
Direct conversion of methane (CH4) to fuels and other high value-added chemicals is an attractive technology in the chemical industry; however, practical challenges to sustainable processes remain. Herein, we report the preparation of a heterostructured Co-doped MgO-based catalyst through topological transformation of a MgCo-layered double hydroxide (LDH) calcination from 200 to 1100 degrees C. Remarkably, the catalyst can activate CH4 coupling to produce C2H6 with a selectivity of 41.60 % within 3 h under full-spectrum irradiation through calcination of LDH at 800 degrees C. Characterization studies and catalytic results suggest that the highly dispersed active sites and large interfaces amongst the Co-doped MgO-based catalysts enable surface activation of CH4 to methyl (CH3*), in turn promoting coupling of CH3* to C2H6. This study introduces a promising pathway for photodriven CH4 coupling to give high value-added chemicals by using layered double hydroxides as a precursor.
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