Direct Photocatalyzed Hydrogen Atom Transfer (HAT) for Aliphatic C-H Bonds Elaboration

Article Chemistry, Organic

Photophysical Properties and Redox Potentials of Photosensitizers for Organic Photoredox Transformations

Yanyu Wu et al.

Summary: This review summarizes the fundamental properties of molecular photosensitizers, including their photophysical and electrochemical attributes, which are crucial determinants of their photocatalytic reactivity.

SYNLETT (2022)

Add to Collection

Article Chemistry, Multidisciplinary

Photochemical Radical C-H Halogenation of Benzyl N-Methyliminodiacetyl (MIDA) Boronates: Synthesis of α-Functionalized Alkyl Boronates

Ling Yang et al.

Summary: A new method was proposed utilizing benzyl N-methyliminodiacetyl (MIDA) boronates for photochemical radical C-H halogenation, enabling successful fluorination, chlorination, and bromination reactions. The resulting brominated product could be further transformed into a variety of organic compounds, including those difficult to form with alpha-halo sp(2)-B boronate esters, by reaction with different nucleophiles. An activation effect of the B(MIDA) moiety was discovered.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Add to Collection

Article Chemistry, Multidisciplinary

Three-Component Alkene Difunctionalization by Direct and Selective Activation of Aliphatic C-H Bonds

Sheng Xu et al.

Summary: Catalytic alkene difunctionalization using decatungstate photo-HAT and nickel catalysis allows for the direct activation of aliphatic C-H bonds, enabling the installation of highly functionalized C(sp(3))-hybrid centers. This strategy demonstrates practicality in selective late-stage functionalization of natural products and concise synthesis of pharmaceutically relevant molecules.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Add to Collection

Article Chemistry, Multidisciplinary

Practical and Selective sp3 C-H Bond Chlorination via Aminium Radicals

Alastair J. McMillan et al.

Summary: The study introduces a general and practical photochemical strategy for the site-selective chlorination of sp(3) C-H bonds, achieving high selectivity through maximizing both polar and steric effects.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Add to Collection

Article Chemistry, Organic

Photocatalytic Carbonylation Strategies: A Recent Trend in Organic Synthesis

Jitender Singh et al.

Summary: Photocatalytic radical carbonylation strategies have garnered attention in recent decades as a powerful tool in organic synthesis by incorporating carbon monoxide into organic molecules. These strategies rely on the generation of an acyl radical as a key intermediate, typically through high-intensity light-induced transition-metal catalysis or visible-light-induced photocatalysis.

JOURNAL OF ORGANIC CHEMISTRY (2021)

Add to Collection

Article Chemistry, Organic

Neutral-Eosin Y-Catalyzed Regioselective Hydroacylation of Aryl Alkenes under Visible-Light Irradiation

Haiwang Liu et al.

Summary: Styrene derivatives were hydroacylated with exclusive anti-Markovnikov selectivity using neutral eosin Y as a direct hydrogen-atom-transfer catalyst under visible-light irradiation, giving moderate to high yields of the corresponding products. The acyl radical intermediate was generated through a direct HAT process induced by photoexcited eosin Y, followed by subsequent addition to styrenes and a reverse HAT process to generate the ketone products.

SYNLETT (2021)

Add to Collection

Article Chemistry, Physical

Recent Advances in Copper Promoted Inert C(sp3)-H Functionalization

Yuhang Yang et al.

Summary: This article reviews the main progress of copper-promoted inert C(sp(3))-H functionalization in establishing different types of bonds, presenting reaction characteristics, proposed mechanisms, and future development trends in this field.

ACS CATALYSIS (2021)

Add to Collection

Review Chemistry, Multidisciplinary

Synthetic and Mechanistic Implications of Chlorine Photoelimination in Nickel/Photoredox C(sp3)-H Cross-Coupling

Stavros K. Kariofillis et al.

Summary: In recent years, the development of light-driven reactions has made significant advancements in synthetic organic chemistry, particularly in combining photoredox and nickel catalysis for challenging cross-coupling reactions. The question of whether photo-induced activation of the nickel catalyst itself could lead to new approaches to cross-coupling has been explored. By utilizing a visible-light-driven mechanism for chlorine radical formation and conducting mechanistic investigations on organometallic Ni complexes relevant to cross-coupling, the study aims to facilitate new catalyst design and develop novel synthetic methods.

ACCOUNTS OF CHEMICAL RESEARCH (2021)

Add to Collection

Review Chemistry, Applied

Photochemical and Electrochemical Strategies towards Benzylic C-H Functionalization: A Recent Update

Monica Oliva et al.

Summary: This review discusses recent advances in benzylic C-H functionalization using organic radical strategies involving photochemistry and electrochemistry as sustainable tools. The potential and prospects of this field are highlighted, along with mechanistic details of typical reactions to aid researchers in exploring new discoveries and opportunities.

ADVANCED SYNTHESIS & CATALYSIS (2021)

Add to Collection

Review Chemistry, Multidisciplinary

Quinuclidine and its derivatives as hydrogen-atom-transfer catalysts in photoinduced reactions

Wei Xiao et al.

Summary: Quinuclidine and its derivatives as HAT catalysts show unique characteristics in direct C == H functionalization of compounds with various groups by abstracting electron-rich and hydridic hydrogens. Their application potential in this field is highlighted due to these features.

CHINESE CHEMICAL LETTERS (2021)

Add to Collection

Review Chemistry, Physical

Photogenerated electrophilic radicals for the umpolung of enolate chemistry

Giovanni V. A. Lenardon et al.

Summary: Enolate chemistry is commonly used for C-C bond formation, but a new trend of reversed-polarity equivalents utilizing electrophilic radicals is emerging. Visible light photoredox catalysis is crucial for generating these radicals, allowing for their broad application in synthetic routes.

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY C-PHOTOCHEMISTRY REVIEWS (2021)

Add to Collection

Article Chemistry, Multidisciplinary

Site-Selective Direct C-H Pyridylation of Unactivated Alkanes by Triplet Excited Anthraquinone

Wooseok Lee et al.

Summary: A novel modular photochemical platform for site-selective C-H pyridylation of unactivated hydrocarbons in chemical feedstocks has been developed, allowing for direct construction of high-value-added compounds under ambient reaction conditions. The system shows high levels of site selectivity and is applicable to a variety of linear-, branched-, and cyclo-alkanes as well as more complex molecules under visible-light conditions.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

Add to Collection

Article Chemistry, Multidisciplinary

Photochemical C-H Activation Enables Nickel-Catalyzed Olefin Dicarbofunctionalization

Mark W. Campbell et al.

Summary: Alkenes, ethers, and alcohols are commonly used bulk reagents in the chemistry community, serving as fuels and solvents in industries such as petrochemical, pharmaceutical, and agrochemical. However, their utilization as building blocks for complex small molecules is limited by the need for prefunctionalization to achieve high selectivity.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

Add to Collection

Article Chemistry, Organic

A Modular, Argon-Driven Flow Platform for Natural Product Synthesis and Late-Stage Transformations

Merlin Kleoff et al.

Summary: A modular flow platform was designed for natural product synthesis, utilizing interchangeable 3D-printed components for flexible reaction setups. By adopting liquid- to gas-driven flow, reagent and solvent waste is minimized, leading to a sustainable profile. Schlenk-in-flow techniques were developed for safe handling of sensitive reagents, enabling reproducible transformations in natural product synthesis.

ORGANIC LETTERS (2021)

Add to Collection

Article Chemistry, Organic

Visible-Light Decatungstate/Disulfide Dual Catalysis for the HydroFunctionalization of Styrenes

Alexis Prieto et al.

Summary: An efficient photoredox system based on decatungstate/disulfide catalysts was developed for the hydrofunctionalization of styrenes. The use of disulfide as a cocatalyst was crucial for enhancing reaction efficiency, allowing for the synthesis of a wide variety of useful building blocks and high-value molecules from simple starting materials, such as amides and unsymmetrical ketones.

ORGANIC LETTERS (2021)

Add to Collection

Article Chemistry, Organic

Synthesis of Unnatural α-Amino Acids via Photoinduced Decatungstate-Catalyzed Giese Reactions of Aldehydes

Xinmou Wang et al.

Summary: The study introduces an efficient and general method for synthesizing gamma-carbonyl alpha-amino acids through photoinduced decatungstate-catalyzed Giese reactions of readily available aldehydes as radical precursors. The mild and robust method is compatible with a wide array of functional groups and has a broad substrate scope. The utility of the method was demonstrated by modifying several amino acid bearing drugs and natural products.

ORGANIC LETTERS (2021)

Add to Collection

Article Chemistry, Multidisciplinary

Photoinduced Activation of Unactivated C(sp3)-H Bonds and Acylation Reactions

Chen-Chao Ren et al.

Summary: An efficient and mild C(sp(3))-H acylation method has been developed based on the direct conversion of stable amides. This photoredox cross-coupling of amides and methylbenzenes for aromatic ketones is enabled by cheap benzophenone photocatalyst and nickel catalyst, achieving high yields (up to 90%). The benzophenone catalyst with electron-withdrawing groups promotes hydrogen atom transfer efficiency, contributing to increased yields.

CHEMISTRYSELECT (2021)

Add to Collection

Article Chemistry, Multidisciplinary

Decatungstate as a direct hydrogen atom transfer photocatalyst for synthesis of trifluromethylthioesters from aldehydes

Xiaochen Wang et al.

Summary: A versatile and mild protocol for trifluoromethylthiolation reactions of aldehydes has been developed, catalyzed by a decatungstate hydrogen atom transfer photocatalyst under redox-neutral conditions. The protocol is highly selective, operationally simple, and compatible with a wide array of sensitive functional groups, making it convenient for late-stage functionalization of bioactive molecules in drug discovery.

CHINESE CHEMICAL LETTERS (2021)

Add to Collection

Article Chemistry, Multidisciplinary

N-Ammonium Ylide Mediators for Electrochemical C-H Oxidation

Masato Saito et al.

Summary: This translation discusses the importance of site-specific C-H bond oxidation in organic synthesis and the current limitations of chemical reagents in achieving this transformation. It introduces a platform using N-ammonium ylides as oxidants for site-specific, chemoselective C-H oxidation, which is guided by computation and can be applied to real-world problems in the agricultural and pharmaceutical sectors.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

Add to Collection

Article Chemistry, Organic

Asymmetric Photocatalytic C(sp3)-H Bond Addition to α-Substituted Acrylates

Zhen-Yao Dai et al.

Summary: The asymmetric functionalization of inert C(sp(3))-H bonds was achieved using a photocatalytic method with TBADT and chiral phosphoric acid, allowing rapid synthesis of enantioenriched astereogenic esters from simple raw materials.

ORGANIC LETTERS (2021)

Add to Collection

Article Chemistry, Organic

Decatungstate as Direct Hydrogen Atom Transfer Photocatalyst for SOMOphilic Alkynylation

Luca Capaldo et al.

Summary: A versatile approach for alkynylation of various aliphatic hydrogen donors including alkanes was achieved using tetrabutylammonium decatungstate as a photocatalyst. The reaction mechanism involved generating organoradicals from C-H/Si-H bonds followed by SOMOphilic alkynylation to form internal alkynes. The impact of different radicofugal groups on the reaction outcome was evaluated through experimental and computational methods.

ORGANIC LETTERS (2021)

Add to Collection

Article Chemistry, Organic

Acylation of Arenes with Aldehydes through Dual C-H Activations by Merging Photocatalysis and Palladium Catalysis

Haiyang Wang et al.

Summary: An acylation reaction of arenes with aldehydes through dual CH activations at room temperature was reported. The reaction was initiated by phenanthraquinone-catalyzed hydrogen atom transfer from aldehyde under visible light irradiation, followed by the merging of the aldehyde-derived acyl radical with palladium-catalyzed activation of arenes to afford the cross coupling products.

ORGANIC LETTERS (2021)

Add to Collection

Article Chemistry, Organic

Cooperative Hydrogen Atom Transfer: From Theory to Applications

Padmanabha V. Kattamuri et al.

Summary: Hydrogen atom transfer (HAT) is a fundamental transformation in organic chemistry that allows for the interconversion of different species through the concerted movement of a proton and an electron. Cooperative HAT reactions have important implications in thermochemistry and can be used as a design principle in organic chemistry for dehydrogenative and hydrogenative reactions. This overview aims to highlight the exciting reactivity possible with cHAT and inspire further developments in this mechanistic approach.

SYNLETT (2021)

Add to Collection

Article Multidisciplinary Sciences

Photocatalytic three-component asymmetric sulfonylation via direct C(sp3)-H functionalization

Shi Cao et al.

Summary: The study demonstrates the use of a dual asymmetric photocatalyst leading to the development of asymmetric sulfonylation involving direct functionalization of cycloalkanes, alkanes, toluene derivatives or ethers.

NATURE COMMUNICATIONS (2021)

Add to Collection

Article Chemistry, Multidisciplinary

C-H Functionalization via Electrophotocatalysis and Photoelectrochemistry: Complementary Synthetic Approach

Tomas Hardwick et al.

Summary: Photoelectrochemical cells are an important tool for energy and environmental applications, with potential for organic synthesis. The merger of photochemistry and electrochemistry is seen as a new strategy for sustainable synthesis methods. By combining electrochemistry and photoredox catalysis, PEC-driven organic synthesis can achieve difficult reactions in an environmentally friendly manner.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2021)

Add to Collection

Article Chemistry, Multidisciplinary

Borrowing Hydrogen for Organic Synthesis

Benjamin G. Reed-Berendt et al.

Summary: Borrowing hydrogen is a process used to diversify the synthetic utility of commodity alcohols by oxidizing alcohols to form reactive carbonyl compounds, which can undergo various transformations before the catalyst regenerates. This method has shown significant advances in recent decades, showcasing the diversity of catalysts available and highlighting the potential for further development.

ACS CENTRAL SCIENCE (2021)

Add to Collection

Article Chemistry, Multidisciplinary

Decatungstate-Mediated C(sp3)-H Heteroarylation via Radical-Polar Crossover in Batch and Flow

Ting Wan et al.

Summary: The study developed an important photocatalytic strategy for the regioselective C(sp(3))-H functionalization of organic molecules, demonstrating high functional group tolerance and scalability, suitable for late-stage functionalization of biologically relevant molecules.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Add to Collection

Article Chemistry, Organic

Decatungstate-Photocatalyzed Addition of Lactones to [60]Fullerene

Nikitas G. Malliaros et al.

Summary: A new one-step method for functionalizing C-60 with lactones has been developed, leading to the synthesis of a previously unknown class of materials, namely 1-lactonyl-2-hydro[60]fullerenes. The mechanism of this reaction has been proposed based on the structure of reaction products and deuterium-incorporated experiments.

JOURNAL OF ORGANIC CHEMISTRY (2021)

Add to Collection

Article Chemistry, Multidisciplinary

Decatungstate-Catalyzed C(sp3)-H Sulfinylation: Rapid Access to Diverse Organosulfur Functionality

Patrick J. Sarver et al.

Summary: The study presents a method for converting strong, aliphatic C(sp(3))-H bonds into alkyl sulfinic acids using decatungstate photocatalysis, which can be applied to a variety of C(sp(3))-rich molecules for efficient synthesis of complex sulfur-containing compounds. Furthermore, the method demonstrates potential for divergent synthesis of pharmaceutically relevant molecules through diversification of the sulfinic acid products into various medicinally relevant functional groups.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

Add to Collection

Article Chemistry, Organic

Photocatalytic C-H Trifluoromethylthiolation by the Decatungstate Anion

Tobias E. Schirmer et al.

Summary: A broadly applicable method for trifluorome-thylthiolation of various types of C-H bonds using decatungstate anion as the sole catalyst has been developed, achieving good regioselectivities in 40 examples, including natural product derivatization. Additionally, SCF3-drug analogues were synthesized by subsequent functionalization of the SCF3 products, highlighting the importance of this photocatalyzed C-H functionalization.

ORGANIC LETTERS (2021)

Add to Collection

Article Chemistry, Organic

C-H Alkylation of Aldehydes by Merging TBADT Hydrogen Atom Transfer with Nickel Catalysis

Vetrivelan Murugesan et al.

Summary: The site-selective C-H functionalization using the dual Ni/photoredox system has been successfully employed for generating acyl radicals from aldehydes to produce ketones. Furthermore, a new cross-coupling reaction via C-N bond cleavage using nickel and TBADT catalyst has been developed, providing a broad spectrum of functional group-tolerant ketones.

ORGANIC LETTERS (2021)

Add to Collection

Article Chemistry, Organic

Multicomponent Synthesis of α-Branched Tertiary and Secondary Amines by Photocatalytic Hydrogen Atom Transfer Strategy

Xu-Kuan Qi et al.

Summary: A multicomponent carbonyl alkylative amination reaction using tetrabutylammonium decatungstate as a photocatalyst was described. Various N-arylamines, aldehydes, and hydrocarbons were examined as reaction substrates, yielding the corresponding alpha-branched tertiary and secondary amines in good to moderate yields. The reaction proceeds through the generation of alkyl radicals via a light-promoted hydrogen atom transfer process followed by free radical addition to iminium ions generated in situ.

ORGANIC LETTERS (2021)

Add to Collection

Article Chemistry, Organic

Direct C(sp3)-H Cyanation Enabled by a Highly Active Decatungstate Photocatalyst

Kunsoon Kim et al.

Summary: A highly efficient, direct C(sp(3))-H cyanation method was developed under mild photocatalytic conditions, allowing for the direct cyanation of various C(sp(3))-H substrates with excellent functional group tolerance. Complex natural products and bioactive compounds can be efficiently cyanated using this method.

ORGANIC LETTERS (2021)

Add to Collection

Article Chemistry, Physical

Palladium-Catalyzed Allylic Alkylation via Photocatalytic Nucleophile Generation

Yang Shen et al.

Summary: A rapid synthetic method for a target compound has been developed by combining photocatalysis and palladium catalysis, demonstrating an atom-economic and environmentally friendly strategy. Experimental results suggest that this method has high synthetic utility.

ACS CATALYSIS (2021)

Add to Collection

Review Chemistry, Physical

Photoinduced intermolecular hydrogen atom transfer reactions in organic synthesis

Hui Cao et al.

Summary: HAT technology provides a simple method to generate open-shell radical intermediates from R-H bonds, while photoinduced intermolecular HAT reactions have seen significant developments in efficiency, selectivity, and versatility, offering new opportunities for green synthesis.

CHEM CATALYSIS (2021)

Add to Collection

Article Chemistry, Multidisciplinary

Emergent synthetic methods for the modular advancement of sp3-rich fragments

Max J. Caplin et al.

Summary: Fragment-based drug discovery is a crucial technology for delivering clinical candidates, but the development of sp(3)-rich fragments remains challenging. Recent advances in C(sp(3))-H functionalization offer valuable approaches to advancing fragment hits by 'growing' functionalized rings and chains from unconventional, carbon-centered vectors.

CHEMICAL SCIENCE (2021)

Add to Collection

Article Chemistry, Organic

A computational study of site-selective hydrogen abstraction by sulfate radical anion

Masahiro Ueda et al.

Summary: The selective hydrogen abstraction reactions on sp(3) carbons with oxyradicals were investigated using ab initio and DFT calculations. It was found that beta-hydrogen abstraction was favorable, consistent with experimental findings. NBO analysis revealed that the transferred hydrogen atom is partially positively charged when abstracted by an oxyradical, and hydrogens bonded to the most positively charged carbon in the substrate were predominantly abstracted, providing a simple compass for predicting regioselectivity in the functionalization of C(sp(3))-H bonds with oxyradicals.

ORGANIC & BIOMOLECULAR CHEMISTRY (2021)

Add to Collection

Article Chemistry, Multidisciplinary

Bio-based crotonic acid from polyhydroxybutyrate: synthesis and photocatalyzed hydroacylation

Adriano Parodi et al.

Summary: A novel thermolytic distillation process was developed to depolymerize polyhydroxybutyrate (PHB) for selective production of crotonic acid. The study also investigated the versatility of crotonic acid as a platform chemical through a photochemical approach, achieving satisfactory functionalization independently of the source of crotonic acid.

GREEN CHEMISTRY (2021)

Add to Collection

Article Chemistry, Multidisciplinary

Photoelectrochemical cross-dehydrogenative coupling of benzothiazoles with strong aliphatic C-H bonds†

Luca Capaldo et al.

Summary: A novel photoelectrochemical strategy was developed for the cross-dehydrogenative coupling of unactivated aliphatic hydrogen donors with benzothiazoles. By using a specific photocatalyst to activate strong C(sp(3))-H bonds in the substrates, while utilizing electrochemistry to scavenge extra electrons, the reaction was efficiently achieved.

CHEMICAL COMMUNICATIONS (2021)

Add to Collection

Review Chemistry, Multidisciplinary

Visible light photocatalysis in the late-stage functionalization of pharmaceutically relevant compounds

Rolando Cannalire et al.

Summary: Late stage functionalization is a powerful tool for accelerating the identification of structure-activity relationships and optimizing ADME profiles of drugs. Visible-light photocatalysis offers a smooth and clean functionalization approach for drugs, with a critical assessment of current literature and highlighting expected future progress and potential applications in the field.

CHEMICAL SOCIETY REVIEWS (2021)

Add to Collection

Review Chemistry, Multidisciplinary

Recent advances in the chemistry of ketyl radicals

Aron Peter et al.

Summary: Ketyl radicals are important reactive intermediates in synthesis, which can be generated through various methods and play crucial roles in new synthetic protocols. Research focuses on innovation in generation pathways, applications in new synthetic schemes, strategies for enantioselectivity control, and detailed reaction mechanisms.

CHEMICAL SOCIETY REVIEWS (2021)

Add to Collection

Review Chemistry, Organic

Recent advances in visible-light photocatalytic deuteration reactions

Rong Zhou et al.

Summary: Deuterated organic compounds are widely used in various fields such as medicinal chemistry, mechanistic studies, and quantitative analyses. Photocatalytic deuteration has emerged as a reliable platform for generating deuterated organic molecules, particularly pharmaceutical compounds, with advantages such as mild conditions and good site selectivity. This review summarizes recent advances in visible-light photocatalytic deuteration reactions based on the type of bond deuterated.

ORGANIC CHEMISTRY FRONTIERS (2021)

Add to Collection

Article Chemistry, Multidisciplinary

C1 Oxidation/C2 Reduction Isomerization of Unprotected Aldoses Induced by Light/Ketone

Yusuke Masuda et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Add to Collection

Article Chemistry, Multidisciplinary

Green Metal-Free Photochemical Hydroacylation of Unactivated Olefins

Errika Voutyritsa et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Add to Collection

Review Chemistry, Physical

Recent Development on Cp*Ir(III)-Catalyzed C-H Bond Functionalization

Xianwei Li et al.

CHEMCATCHEM (2020)

Add to Collection

Review Chemistry, Multidisciplinary

N-Centered Radical Directed Remote C-H Bond Functionalization via Hydrogen Atom Transfer

Gautam Kumar et al.

CHEMISTRY-AN ASIAN JOURNAL (2020)

Add to Collection

Review Chemistry, Organic

The Dark Side of Photocatalysis: One Thousand Ways to Close the Cycle

Luca Capaldo et al.

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY (2020)

Add to Collection

Review Chemistry, Multidisciplinary

Photoredox-Mediated Net-Neutral Radical/Polar Crossover Reactions

Rebecca J. Wiles et al.

ISRAEL JOURNAL OF CHEMISTRY (2020)

Add to Collection

Article Chemistry, Multidisciplinary

Nickel/Photo-Cocatalyzed Asymmetric Acyl-Carbamoylation of Alkenes

Pei Fan et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

Add to Collection

Article Chemistry, Multidisciplinary

Electrophotocatalytic C-H Functionalization of Ethers with High Regioselectivity

He Huang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

Add to Collection

Article Chemistry, Multidisciplinary

Enantioselective C-H Lactonization of Unactivated Methylenes Directed by Carboxylic Acids

Marco Cianfanelli et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

Add to Collection

Article Chemistry, Multidisciplinary

Photocontrolled Radical Polymerization from Hydridic C-H Bonds

Erin E. Stache et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

Add to Collection

Article Chemistry, Organic

Coupling Reaction between Aldehydes and Non-Activated Hydrocarbons via the Reductive Radical-Polar Crossover Pathway

Kenzo Yahata et al.

ORGANIC LETTERS (2020)

Add to Collection

Article Chemistry, Physical

Deuteration of Formyl Groups via a Catalytic Radical H/D Exchange Approach

Yueteng Zhang et al.

ACS CATALYSIS (2020)

Add to Collection

Article Chemistry, Multidisciplinary

Photocatalytic α-Tertiary Amine Synthesis via C-H Alkylation of Unmasked Primary Amines

Alison S. H. Ryder et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Add to Collection

Article Chemistry, Multidisciplinary

Predictable Selectivity in Remote C-H Oxidation of Steroids: Analysis of Substrate Binding Mode

Giorgio Olivo et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Add to Collection

Review Chemistry, Physical

Anthraquinones: Versatile Organic Photocatalysts

Javier Cervantes-Gonzalez et al.

CHEMCATCHEM (2020)

Add to Collection

Article Chemistry, Multidisciplinary

Visible Light-Enabled sp3-C-H Functionalization with Chloro- and Bromoalkynes: Chemoselective Route to Vinylchlorides or Alkynes

Tapas Adak et al.

CHEMISTRY-A EUROPEAN JOURNAL (2020)

Add to Collection

Article Chemistry, Multidisciplinary

Intermolecular Radical C-H Bond Activation: A Powerful Tool for Late Stage Functionalization

Fabrice Denes

CHIMIA (2020)

Add to Collection

Article Chemistry, Organic

Benzylic Hydroperoxidation via Visible-Light-Induced Csp3-H Activation

Joan Inoa et al.

JOURNAL OF ORGANIC CHEMISTRY (2020)

Add to Collection

Article Multidisciplinary Sciences

Photoinduced site-selective alkenylation of alkanes and aldehydes with aryl alkenes

Hui Cao et al.

NATURE COMMUNICATIONS (2020)

Add to Collection

Article Chemistry, Physical

Site-Selective and Product Chemoselective Aliphatic C-H Bond Hydroxylation of Polyhydroxylated Substrates

Margarida Borrell et al.

ACS CATALYSIS (2020)

Add to Collection

Article Chemistry, Physical

Light-Mediated Asymmetric Aliphatic C-H Alkylation with Hydrogen Atom Transfer Catalyst and Chiral Phosphoric Acid

Zhen-Yao Dai et al.

ACS CATALYSIS (2020)

Add to Collection

Article Chemistry, Multidisciplinary

Nickel/Photoredox-Catalyzed Methylation of (Hetero)aryl Chlorides Using Trimethyl Orthoformate as a Methyl Radical Source

Stavros K. Kariofillis et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

Add to Collection

Article Chemistry, Multidisciplinary

The merger of decatungstate and copper catalysis to enable aliphatic C(sp3)-H trifluoromethylation

Patrick J. Sarver et al.

NATURE CHEMISTRY (2020)

Add to Collection

Article Chemistry, Organic

Acylation of Aryl Halides and α-Bromo Acetates with Aldehydes Enabled by Nickel/TBADT Cocatalysis

Pei Fan et al.

ORGANIC LETTERS (2020)

Add to Collection

Review Chemistry, Multidisciplinary

Generation of Alkyl Radicals: From the Tyranny of Tin to the Photon Democracy

Stefano Crespi et al.

CHEMICAL REVIEWS (2020)

Add to Collection

Article Chemistry, Multidisciplinary

Scalable Photoelectrochemical Dehydrogenative Cross-Coupling of Heteroarenes with Aliphatic C-H Bonds

Pin Xu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Add to Collection

Review Chemistry, Organic

When metal-catalyzed C-H functionalization meets visible-light photocatalysis

Lucas Guillemard et al.

BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY (2020)

Add to Collection

Article Chemistry, Organic

Visible-Light Photocatalysis of Eosin Y: HAT and Complementing MS-CPET Strategy to Trifluoromethylation of β-Ketodithioesters with Langlois' Reagent

Sonam Soni et al.

JOURNAL OF ORGANIC CHEMISTRY (2020)

Add to Collection

Article Chemistry, Multidisciplinary

A Radical Smiles Rearrangement Promoted by Neutral Eosin Y as a Direct Hydrogen Atom Transfer Photocatalyst

Jianming Yan et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

Add to Collection

Article Chemistry, Multidisciplinary

Rational Design of Triplet Sensitizers for the Transfer of Excited State Photochemistry from UV to Visible

Luke D. Elliott et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

Add to Collection

Review Chemistry, Organic

H Photosensitized direct C-H fluorination and trifluoromethylation in organic synthesis

Shahboz Yakubov et al.

BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY (2020)

Add to Collection

Review Chemistry, Organic

Recent developments in enantioselective photocatalysis

Callum Prentice et al.

BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY (2020)

Add to Collection

Article Chemistry, Multidisciplinary

Visible-Light-Enabled C-H Functionalization by a Direct Hydrogen Atom Transfer Uranyl Photocatalyst

Jipan Yu et al.

CHEMISTRY-A EUROPEAN JOURNAL (2020)

Add to Collection

Article Chemistry, Multidisciplinary

Photochemical Functionalization of Heterocycles with EBX Reagents: C-H Alkynylation versus Deconstructive Ring Cleavage

Errika Voutyritsa et al.

CHEMISTRY-A EUROPEAN JOURNAL (2020)

Add to Collection

Article Chemistry, Multidisciplinary

Phenylglyoxylic Acid: An Efficient Initiator for the Photochemical Hydrogen Atom Transfer C-H Functionalization of Heterocycles

Giorgos N. Papadopoulos et al.

CHEMSUSCHEM (2020)

Add to Collection

Article Chemistry, Applied

Optimization of a Decatungstate-Catalyzed C(sp3)-H Alkylation Using a Continuous Oscillatory Millistructured Photoreactor

Zhenghui Wen et al.

ORGANIC PROCESS RESEARCH & DEVELOPMENT (2020)

Add to Collection

Article Multidisciplinary Sciences

C(sp3)-H functionalizations of light hydrocarbons using decatungstate photocatalysis in flow

Gabriele Laudadio et al.

SCIENCE (2020)

Add to Collection

Review Chemistry, Organic

Carbonyl-Photoredox/Metal Dual Catalysis: Applications in Organic Synthesis

Da-Liang Zhu et al.

SYNTHESIS-STUTTGART (2020)

Add to Collection

Article Chemistry, Organic

Aerobic C-H Functionalization Using Pyrenedione as the Photocatalyst

Yuannian Zhang et al.

SYNTHESIS-STUTTGART (2020)

Add to Collection

Article Chemistry, Physical

Direct C-H Arylation of Aldehydes by Merging Photocatalyzed Hydrogen Atom Transfer with Palladium Catalysis

Lu Wang et al.

ACS CATALYSIS (2020)

Add to Collection

Article Chemistry, Physical

Antimony-Oxo Porphyrins as Photocatalysts for Redox-Neutral C-H to C-C Bond Conversion

Luca Capaldo et al.

ACS CATALYSIS (2020)

Add to Collection

Article Chemistry, Organic

Visible Light-Induced Direct S0 → Tn Transition of Benzophenone Promotes C(sp3)-H Alkynylation of Ethers and Amides

Koki Matsumoto et al.

JOURNAL OF ORGANIC CHEMISTRY (2020)

Add to Collection

Article Chemistry, Multidisciplinary

Manganese-Catalyzed Oxidative Azidation of C(sp3)-H Bonds under Electrophotocatalytic Conditions

Linbin Niu et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

Add to Collection

Article Chemistry, Organic

Light-Mediated Difluoromethylthiolation of Aldehydes with a Hydrogen Atom Transfer Photocatalyst

Jianyang Dong et al.

ORGANIC LETTERS (2020)

Add to Collection

Article Chemistry, Organic

Facile Thiol-Ene Click Protocol Using Benzil as Sensitizer and White LED as Light Source

Anupam Das et al.

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY (2020)

Add to Collection

Article Chemistry, Organic

A scalable continuous photochemical process for the generation of aminopropylsulfones

Stefano Bonciolini et al.

ORGANIC & BIOMOLECULAR CHEMISTRY (2020)

Add to Collection

Article Chemistry, Multidisciplinary

C-H functionalization reactions enabled by hydrogen atom transfer to carbon-centered radicals

Sumon Sarkar et al.

CHEMICAL SCIENCE (2020)

Add to Collection

Review Chemistry, Organic

Photoinduced Decatungstate-Catalyzed C-H Functionalization

Xiaoya Yuan et al.

CHINESE JOURNAL OF ORGANIC CHEMISTRY (2020)

Add to Collection

Article Chemistry, Multidisciplinary

Transition metal-free cross-dehydrogenative arylation of unactivated benzylic C-H bonds

Andrew R. A. Spencer et al.

CHEMICAL COMMUNICATIONS (2020)

Add to Collection

Article Chemistry, Multidisciplinary

Diverse strategies for transition metal catalyzed distal C(sp3)-H functionalizations

Jayabrata Das et al.

CHEMICAL SCIENCE (2020)

Add to Collection

Review Chemistry, Multidisciplinary

Catalytic generation of alkoxy radicals from unfunctionalized alcohols

Elaine Tsui et al.

CHEMICAL SCIENCE (2020)

Add to Collection

Article Chemistry, Multidisciplinary

Formyl-selective deuteration of aldehydes with D2O via synergistic organic and photoredox catalysis

Jianyang Dong et al.

CHEMICAL SCIENCE (2020)

Add to Collection

Review Chemistry, Multidisciplinary

Photocatalytic hydrogen atom transfer: the philosopher's stone for late-stage functionalization?

Luca Capaldo et al.

GREEN CHEMISTRY (2020)

Add to Collection

Article Chemistry, Multidisciplinary

Pyrenediones as versatile photocatalysts for oxygenation reactions with in situ generation of hydrogen peroxide under visible light

Yuannian Zhang et al.

GREEN CHEMISTRY (2020)

Add to Collection

Article Chemistry, Multidisciplinary

Visible light driven deuteration of formyl C-H and hydridic C(sp3)-H bonds in feedstock chemicals and pharmaceutical molecules

Yulong Kuang et al.

CHEMICAL SCIENCE (2020)

Add to Collection

Article Chemistry, Multidisciplinary

Synthesis of amino-diamondoid pharmacophores via photocatalytic C-H aminoalkylation

William K. Weigel et al.

CHEMICAL COMMUNICATIONS (2020)

Add to Collection

Review Chemistry, Multidisciplinary

Iron- and cobalt-catalyzed C(sp3)-H bond functionalization reactions and their application in organic synthesis

Yungen Liu et al.

CHEMICAL SOCIETY REVIEWS (2020)

Add to Collection

Review Chemistry, Multidisciplinary

Flow Photochemistry: Shine Some Light on Those Tubes!

Carlo Sambiagio et al.

TRENDS IN CHEMISTRY (2020)

Add to Collection

Article Chemistry, Multidisciplinary

The Dual Role of Benzophenone in Visible-Light/Nickel Photoredox-Catalyzed C-H Arylations: Hydrogen-Atom Transfer and Energy Transfer

Abhishek Dewanji et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

Add to Collection

Article Chemistry, Physical

Controlled Photocatalytic Hydrocarbon Oxidation by Uranyl Complexes

Polly L. Arnold et al.

CHEMCATCHEM (2019)

Add to Collection

Article Chemistry, Organic

Evaluation of Polar Effects in Hydrogen Atom Transfer Reactions from Activated Phenols

Massimo Bietti et al.

JOURNAL OF ORGANIC CHEMISTRY (2019)

Add to Collection

Article Chemistry, Organic

Efficiency and Selectivity Aspects in the C-H Functionalization of Aliphatic Oxygen Heterocycles by Photocatalytic Hydrogen Atom Transfer

Carlotta Raviola et al.

SYNLETT (2019)

Add to Collection

Article Chemistry, Physical

Visible Light Uranyl Photocatalysis: Direct C-H to C-C Bond Conversion

Luca Capaldo et al.

ACS CATALYSIS (2019)

Add to Collection

Review Chemistry, Multidisciplinary

Palladium-Catalyzed C(sp3)-H Bond Functionalization of Aliphatic Amines

Chuan He et al.

CHEM (2019)

Add to Collection

Article Chemistry, Multidisciplinary

Formal Hydroformylation of α,β-Unsaturated Carboxylic Acids under Photoexcited Ketone Catalysis

Kailong Zhu et al.

CHEMISTRY LETTERS (2019)

Add to Collection

Article Chemistry, Multidisciplinary

Organocatalytic Transformation of Aldehydes to Thioesters with Visible Light

Yueteng Zhang et al.

CHEMISTRY-A EUROPEAN JOURNAL (2019)

Add to Collection

Article Chemistry, Organic

Radical Addition to N-Tosylimines via C-H Activation Induced by Decatungstate Photocatalyst

Vyacheslav I. Supranovich et al.

ORGANIC LETTERS (2019)

Add to Collection

Article Chemistry, Organic

Oxidation of α-amino acids promoted by the phthalimide N-oxyl radical: A kinetic and product study

Barbara Ticconi et al.

TETRAHEDRON (2019)

Add to Collection

Article Chemistry, Organic

Photocatalysed eosin Y mediated C(sp3)-H alkylation of amine substrates via direct HAT

Vishal Srivastava et al.

TETRAHEDRON LETTERS (2019)

Add to Collection

Article Chemistry, Physical

Catalyst-Controlled C-H Functionalization of Adamantanes Using Selective H-Atom Transfer

Hai-Bin Yang et al.

ACS CATALYSIS (2019)

Add to Collection

Article Chemistry, Applied

Visible-Light-Promoted Oxidative Alkylarylation of N-Aryl/Benzoyl Acrylamides Through Direct C-H Bond Functionalization

Maojian Lu et al.

ADVANCED SYNTHESIS & CATALYSIS (2019)

Add to Collection

Article Chemistry, Multidisciplinary

C-H Alkylation via Multisite-Proton-Coupled Electron Transfer of an Aliphatic C-H Bond

Carla M. Morton et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

Add to Collection

Review Chemistry, Multidisciplinary

Thermal and Photochemical Reduction and Functionalization Chemistry of the Uranyl Dication, [UVIO2]2+

Bradley E. Cowie et al.

CHEMICAL REVIEWS (2019)

Add to Collection

Review Pharmacology & Pharmacy

An overview of late-stage functionalization in today's drug discovery

Michael Moir et al.

EXPERT OPINION ON DRUG DISCOVERY (2019)

Add to Collection

Article Chemistry, Physical

Electrostatic Effects Accelerate Decatungstate-Catalyzed C-H Fluorination Using [18F]- and [19F]NFSI in Small Molecules and Peptide Mimics

Zheliang Yuan et al.

ACS CATALYSIS (2019)

Add to Collection

Article Chemistry, Organic

Visible-Light-Enabled Selective Oxidation of Primary Alcohols through Hydrogen-Atom Transfer and its Application in the Synthesis of Quinazolinones

Qiangqiang Xia et al.

ASIAN JOURNAL OF ORGANIC CHEMISTRY (2019)

Add to Collection

Article Chemistry, Multidisciplinary

Neutral-Eosin-Y-Photocatalyzed Silane Chlorination Using Dichloromethane

Xuanzi Fan et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

Add to Collection

Article Chemistry, Multidisciplinary

Asymmetric Synthesis of 1,4-Dicarbonyl Compounds from Aldehydes by Hydrogen Atom Transfer Photocatalysis and Chiral Lewis Acid Catalysis

Yulong Kuang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

Add to Collection

Article Chemistry, Multidisciplinary

Dual Benzophenone/Copper-Photocatalyzed Giese-Type Alkylation of C(sp3)-H Bonds

Baptiste Abadie et al.

CHEMISTRY-A EUROPEAN JOURNAL (2019)

Add to Collection

Review Chemistry, Multidisciplinary

Rhodium-Catalyzed C(sp2)- or C(sp3)-H Bond Functionalization Assisted by Removable Directing Groups

Supriya Rej et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

Add to Collection

Article Chemistry, Multidisciplinary

Photocatalysis Enables Visible-Light Uncaging of Bioactive Molecules in Live Cells

Haoyan Wang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

Add to Collection

Editorial Material Chemistry, Multidisciplinary

New Roles for Photoexcited Eosin Y in Photochemical Reactions

Dong-Mei Yan et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

Add to Collection

Article Chemistry, Physical

Photocatalytic regio- and stereoselective C(sp3)-H functionalization of benzylic and allylic hydrocarbons as well as unactivated alkanes

Yanjun Li et al.

NATURE CATALYSIS (2019)

Add to Collection

Article Chemistry, Applied

Finding the Perfect Match: A Combined Computational and Experimental Study toward Efficient and Scalable Photosensitized [2+2] Cycloadditions in Flow

Jason D. Williams et al.

ORGANIC PROCESS RESEARCH & DEVELOPMENT (2019)

Add to Collection

Article Polymer Science

The role of ketyl radicals in free radical photopolymerization: new experimental and theoretical insights

Julien Christmann et al.

POLYMER CHEMISTRY (2019)

Add to Collection

Article Chemistry, Multidisciplinary

Photocatalytic hydroacylation of trifluoromethyl alkenes

Pei Fan et al.

CHEMICAL COMMUNICATIONS (2019)

Add to Collection

Article Chemistry, Multidisciplinary

Enzyme-like substrate-selectivity in C-H oxidation enabled by recognition

Giorgio Olivo et al.

CHEMICAL COMMUNICATIONS (2019)

Add to Collection

Review Chemistry, Multidisciplinary

Reductive radical-polar crossover: traditional electrophiles in modern radical reactions

Lena Pitzer et al.

CHEMICAL SCIENCE (2019)

Add to Collection

Article Chemistry, Multidisciplinary

Hydrogen atom transfer from 1,2-and 1,3-diols to the cumyloxyl radical. The role of structural effects on metal-ion induced C-H bond deactivation

Teo Martin et al.

CHEMICAL COMMUNICATIONS (2019)

Add to Collection

Article Chemistry, Multidisciplinary

Recent advances in alkoxy radical-promoted C-C and C-H bond functionalization starting from free alcohols

Xinxin Wu et al.

CHEMICAL COMMUNICATIONS (2019)

Add to Collection

Article Chemistry, Multidisciplinary

Visible-light-mediated deuteration of silanes with deuterium oxide

Rong Zhou et al.

CHEMICAL SCIENCE (2019)

Add to Collection

Article Chemistry, Multidisciplinary

Photochemical reactivity of phenyl (methyl-tetrazolyl) ketone - hydrogen atom transfer vs. electron transfer

Maxime Freneau et al.

NEW JOURNAL OF CHEMISTRY (2019)

Add to Collection

Review Chemistry, Organic

Recent advances in cobalt-catalysed C-H functionalizations

Alessio Baccalini et al.

ORGANIC & BIOMOLECULAR CHEMISTRY (2019)

Add to Collection

Review Chemistry, Physical

Photochemistry of Carbonyl Compounds: Application in Metal-Free Reactions

Juliana A. Dantas et al.

CHEMPHOTOCHEM (2019)

Add to Collection

Article Chemistry, Physical

Site-Selective C-H Functionalization by Decatungstate Anion Photocatalysis: Synergistic Control by Polar and Steric Effects Expands the Reaction Scope

Davide Ravelli et al.

ACS CATALYSIS (2018)

Add to Collection

Article Chemistry, Multidisciplinary

Eosin Y as a Direct Hydrogen-Atom Transfer Photocatalyst for the Functionalization of C-H Bonds

Xuan-Zi Fan et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

Add to Collection

Review Chemistry, Multidisciplinary

Activation and Deactivation Strategies Promoted by Medium Effects for Selective Aliphatic C-H Bond Functionalization

Massimo Bietti

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

Add to Collection

Article Chemistry, Multidisciplinary

Selective C(sp(3))-H Aerobic Oxidation Enabled by Decatungstate Photocatalysis in Flow

Gabriele Laudadio et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

Add to Collection

Article Chemistry, Multidisciplinary

Sulfonamides as new hydrogen atom transfer (HAT) catalysts for photoredox allylic and benzylic C-H arylations

Hirotaka Tanaka et al.

CHEMICAL COMMUNICATIONS (2018)

Add to Collection

Review Chemistry, Multidisciplinary

Electrochemical strategies for C-H functionalization and C-N bond formation

Markus D. Karkas

CHEMICAL SOCIETY REVIEWS (2018)

Add to Collection

Article Chemistry, Multidisciplinary

Site-selectivity in TBADT-photocatalyzed C(sp3)-H Functionalization of Saturated Alcohols and Alkanes

Takahide Fukuyama et al.

CHEMISTRY LETTERS (2018)

Add to Collection

Article Chemistry, Medicinal

Fluorine and Fluorinated Motifs in the Design and Application of Bioisosteres for Drug Design

Nicholas A. Meanwell

JOURNAL OF MEDICINAL CHEMISTRY (2018)

Add to Collection

Article Chemistry, Organic

Hydrogen Atom Transfer from Alkanols and Alkanediols to the Cumyloxyl Radical: Kinetic Evaluation of the Contribution of alpha-C-H Activation and beta-C-H Deactivation

Michela Salamone et al.

JOURNAL OF ORGANIC CHEMISTRY (2018)

Add to Collection

Article Chemistry, Organic

Photoinduced Generation of Acyl Radicals from Simple Aldehydes, Access to 3-Acyl-4-arylcoumarin Derivatives, and Evaluation of Their Antiandrogenic Activities

Kazuki Kawaai et al.

JOURNAL OF ORGANIC CHEMISTRY (2018)

Add to Collection

Article Chemistry, Organic

Evolution of Biocatalytic and Chemocatalytic C-H Functionalization Strategy in the Synthesis of Manzacidin C

Christian R. Zwick et al.

JOURNAL OF ORGANIC CHEMISTRY (2018)

Add to Collection

Article Polymer Science

Cross-linking photopolymerization of monoacrylate initiated by benzophenone

Yasuyuki Sanai et al.

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY (2018)

Add to Collection

Article Chemistry, Multidisciplinary

Remote C-H Hydroxylation by an α-Ketoglutarate-Dependent Dioxygenase Enables Efficient Chemoenzymatic Synthesis of Manzacidin C and Proline Analogs

Christian R. Zwick et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

Add to Collection

Review Chemistry, Organic

Photoorganocatalysis, small organic molecules and light in the service of organic synthesis: the awakening of a sleeping giant

Ioanna K. Sideri et al.

ORGANIC & BIOMOLECULAR CHEMISTRY (2018)

Add to Collection

Article Chemistry, Organic

Enhancing Reactivity and Site-Selectivity in Hydrogen Atom Transfer from Amino Acid C-H Bonds via Deprotonation

Luca Maria Pipitone et al.

ORGANIC LETTERS (2018)

Add to Collection

Review Chemistry, Organic

Remote C-H Functionalization via Selective Hydrogen Atom Transfer

Leah M. Stateman et al.

SYNTHESIS-STUTTGART (2018)

Add to Collection

Article Chemistry, Organic

Photocatalytic alkoxy radical-mediated transformations

Jing-Jing Guo et al.

TETRAHEDRON LETTERS (2018)

Add to Collection

Review Chemistry, Multidisciplinary

Advances in Development of C-H Activation/Functionalization Using a Catalytic Directing Group

Omer K. Rasheed et al.

CHEMISTRYSELECT (2018)

Add to Collection

Review Chemistry, Multidisciplinary

The Quest for Selectivity in Hydrogen Atom Transfer Based Aliphatic C-H Bond Oxygenation

Michela Milan et al.

ACCOUNTS OF CHEMICAL RESEARCH (2018)

Add to Collection

Review Chemistry, Applied

Visible Light-Induced C-H Bond Functionalization: A Critical Review

Lekkala Revathi et al.

ADVANCED SYNTHESIS & CATALYSIS (2018)

Add to Collection

Article Chemistry, Multidisciplinary

Site-Selective, Late-Stage C-H 18F-Fluorination on Unprotected Peptides for Positron Emission Tomography Imaging

Zheliang Yuan et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

Add to Collection

Article Chemistry, Multidisciplinary

Synthesis of acyl fluorides via photocatalytic fluorination of aldehydic C-H bonds

Michael Meanwell et al.

CHEMICAL COMMUNICATIONS (2018)

Add to Collection

Review Chemistry, Multidisciplinary

A comprehensive overview of directing groups applied in metal-catalysed C-H functionalisation chemistry

Carlo Sambiagio et al.

CHEMICAL SOCIETY REVIEWS (2018)

Add to Collection

Article Chemistry, Multidisciplinary

sp(3) C-H Arylation and Alkylation Enabled by the Synergy of Triplet Excited Ketones and Nickel Catalysts

Yangyang Shen et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

Add to Collection

Review Multidisciplinary Sciences

Enhancing the potential of enantioselective organocatalysis with light

Mattia Silvi et al.

NATURE (2018)

Add to Collection

Article Multidisciplinary Sciences

Direct arylation of strong aliphatic C-H bonds

Ian B. Perry et al.

NATURE (2018)

Add to Collection

Article Chemistry, Organic

Eosin-Mediated Alkylsulfonyl Cyanation of Olefins

Vincent Pirenne et al.

ORGANIC LETTERS (2018)

Add to Collection

Article Chemistry, Physical

Heterogeneous Organocatalysis for Photoredox Chemistry

Aleksandr Savateev et al.

ACS CATALYSIS (2018)

Add to Collection

Editorial Material Chemistry, Multidisciplinary

Uncovering the Complexity of the Simplest Atom Transfer Reaction

Miguel Costas et al.

ACCOUNTS OF CHEMICAL RESEARCH (2018)

Add to Collection

Article Chemistry, Multidisciplinary

Selective C-H Halogenation with a Highly Fluorinated Manganese Porphyrin

Gang Li et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

Add to Collection

Article Chemistry, Physical

Multi-Step Continuous Flow Synthesis of /-Substituted Ketones

Silvia Garbarino et al.

CHEMPHOTOCHEM (2018)

Add to Collection

Review Chemistry, Organic

Hydrogen Atom Transfer (HAT): A Versatile Strategy for Substrate Activation in Photocatalyzed Organic Synthesis

Luca Capaldo et al.

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY (2017)

Add to Collection

Article Chemistry, Multidisciplinary

Radical C(sp3)-H alkenylation, alkynylation and allylation of ethers and amides enabled by photocatalysis

Subhasis Paul et al.

GREEN CHEMISTRY (2017)

Add to Collection

Article Chemistry, Organic

Aerobic Oxidation of 4-Alkyl-N,N-dimethylbenzylamines Catalyzed by N-Hydroxyphthalimide: Protonation-Driven Control over Regioselectivity

Massimo Bietti et al.

JOURNAL OF ORGANIC CHEMISTRY (2017)

Add to Collection

Article Chemistry, Organic

Electronic and Torsional Effects on Hydrogen Atom Transfer from Aliphatic C-H Bonds: A Kinetic Evaluation via Reaction with the Cumyloxyl Radical

Michela Salamone et al.

JOURNAL OF ORGANIC CHEMISTRY (2017)

Add to Collection

Article Chemistry, Organic

Synthesis of Alkylated Pyrimidines via Photoinduced Coupling Using Benzophenone as a Mediator

Shin Kamijo et al.

JOURNAL OF ORGANIC CHEMISTRY (2017)

Add to Collection

Article Chemistry, Organic

Hydrogen Atom Transfer (HAT) Processes Promoted by the Quinolinimide-N-oxyl Radical. A Kinetic and Theoretical Study

Gino A. DiLabio et al.

JOURNAL OF ORGANIC CHEMISTRY (2017)

Add to Collection

Article Chemistry, Organic

Evaluating brominated thioxanthones as organo-photocatalysts

Akila Iyer et al.

JOURNAL OF PHYSICAL ORGANIC CHEMISTRY (2017)

Add to Collection

Article Chemistry, Multidisciplinary

18F-Fluorination of Unactivated C-H Bonds in Branched Aliphatic Amino Acids: Direct Synthesis of Oncological Positron Emission Tomography Imaging Agents

Matthew B. Nodwell et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

Add to Collection

Article Chemistry, Multidisciplinary

Ruthenium-Catalyzed C-H Hydroxylation in Aqueous Acid Enables Selective Functionalization of Amine Derivatives

James B. C. Mack et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

Add to Collection

Article Chemistry, Organic

Photocatalyzed Site-Selective C(sp3)-H Functionalization of Alkylpyridines at Non-Benzylic Positions

Takahide Fukuyama et al.

ORGANIC LETTERS (2017)

Add to Collection

Article Chemistry, Organic

Remote C(sp3)-H Oxygenation of Protonated Aliphatic Amines with Potassium Persulfate

Melissa Lee et al.

ORGANIC LETTERS (2017)

Add to Collection

Article Chemistry, Inorganic & Nuclear

Seven-coordinated chiral uranyl(VI) salen complex as effective catalyst for C-H bond activation of dialkylanilines under visible light

Mohammad Azam et al.

POLYHEDRON (2017)

Add to Collection

Article Multidisciplinary Sciences

Photoredox-catalyzed deuteration and tritiation of pharmaceutical compounds

Yong Yao Loh et al.

SCIENCE (2017)

Add to Collection

Article Chemistry, Organic

Visible light photocatalysis with benzophenone for radical thiol-ene reactions

Manjula Singh et al.

TETRAHEDRON LETTERS (2017)

Add to Collection

Article Chemistry, Multidisciplinary

Toward a mild dehydroformylation using base-metal catalysis

Dylan J. Abrams et al.

CHEMICAL SCIENCE (2017)

Add to Collection

Article Chemistry, Multidisciplinary

Photoredox ketone catalysis for the direct C-H imidation and acyloxylation of arenes

Chandra Bhushan Tripathi et al.

CHEMICAL SCIENCE (2017)

Add to Collection

Article Chemistry, Physical

Tuning Selectivity in Aliphatic C-H Bond Oxidation of N-Alkylamides and Phthalimides Catalyzed by Manganese Complexes

Michela Milan et al.

ACS CATALYSIS (2017)

Add to Collection

Article Chemistry, Physical

Photoredox-Mediated Routes to Radicals: The Value of Catalytic Radical Generation in Synthetic Methods Development

Jennifer K. Matsui et al.

ACS CATALYSIS (2017)

Add to Collection

Article Chemistry, Multidisciplinary

Chemoselective Aliphatic C-H Bond Oxidation Enabled by Polarity Reversal

Valeria Dantignana et al.

ACS CENTRAL SCIENCE (2017)

Add to Collection

Article Chemistry, Multidisciplinary

Highly Enantioselective Oxidation of Nonactivated Aliphatic C-H Bonds with Hydrogen Peroxide Catalyzed by Manganese Complexes

Michela Milan et al.

ACS CENTRAL SCIENCE (2017)

Add to Collection

Review Chemistry, Multidisciplinary

The merger of transition metal and photocatalysis

Jack Twilton et al.

NATURE REVIEWS CHEMISTRY (2017)

Add to Collection

Article Chemistry, Multidisciplinary

Recent developments in transition-metal photoredox-catalysed reactions of carbonyl derivatives

Katarzyna N. Lee et al.

CHEMICAL COMMUNICATIONS (2017)

Add to Collection

Article Chemistry, Multidisciplinary

Supramolecular Recognition Allows Remote, Site-Selective C-H Oxidation of Methylenic Sites in Linear Amines

Giorgio Olivo et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)

Add to Collection

Article Chemistry, Multidisciplinary

Oxyfunctionalization of the Remote C-H Bonds of Aliphatic Amines by Decatungstate Photocatalysis

Danielle M. Schultz et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)

Add to Collection

Article Chemistry, Physical

Selective Photooxidation Reactions using Water-Soluble Anthraquinone Photocatalysts

Wuyuan Zhang et al.

CHEMCATCHEM (2017)

Add to Collection

Review Chemistry, Multidisciplinary

The recent achievements of redox-neutral radical C-C cross-coupling enabled by visible-light

Jin Xie et al.

CHEMICAL SOCIETY REVIEWS (2017)

Add to Collection

Article Chemistry, Multidisciplinary

Cooperative Polar/Steric Strategy in Achieving Site-Selective Photocatalyzed C(sp3)-H Functionalization

Keiichi Yamada et al.

CHEMISTRY-A EUROPEAN JOURNAL (2017)

Add to Collection

Article Chemistry, Multidisciplinary

Selective Aerobic Oxidation of Methylarenes to Benzaldehydes Catalyzed by N-Hydroxyphthalimide and Cobalt(II) Acetate in Hexafluoropropan-2-ol

Eden Gaster et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)

Add to Collection

Article Chemistry, Multidisciplinary

Vinylpyridines as Building Blocks for the Photocatalyzed Synthesis of Alkylpyridines

Luca Capaldo et al.

CHEMISTRY-A EUROPEAN JOURNAL (2017)

Add to Collection

Review Chemistry, Multidisciplinary

Photochemical synthesis: Using light to build C-C bonds under mild conditions

Simone Lazzaroni et al.

COMPTES RENDUS CHIMIE (2017)

Add to Collection

Review Chemistry, Multidisciplinary

Steering Asymmetric Lewis Acid Catalysis Exclusively with Octahedral Metal-Centered Chirality

Lilu Zhang et al.

ACCOUNTS OF CHEMICAL RESEARCH (2017)

Add to Collection

Review Chemistry, Multidisciplinary

Evolution of C-H Bond Functionalization from Methane to Methodology

John F. Hartwig

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2016)

Add to Collection

Review Chemistry, Multidisciplinary

Synthetic Applications of Proton-Coupled Electron Transfer

Emily C. Gentry et al.

ACCOUNTS OF CHEMICAL RESEARCH (2016)

Add to Collection

Review Chemistry, Multidisciplinary

Syntheses and Transformations of α-Amino Acids via Palladium-Catalyzed Auxiliary-Directed sp3 C-H Functionalization

Gang He et al.

ACCOUNTS OF CHEMICAL RESEARCH (2016)

Add to Collection

Review Chemistry, Multidisciplinary

Shining Light on Copper: Unique Opportunities for Visible-Light-Catalyzed Atom Transfer Radical Addition Reactions and Related Processes

Oliver Reiser

ACCOUNTS OF CHEMICAL RESEARCH (2016)

Add to Collection

Review Chemistry, Multidisciplinary

Photoredox Catalysis for the Generation of Carbon Centered Radicals

Jean-Philippe Goddard et al.

ACCOUNTS OF CHEMICAL RESEARCH (2016)

Add to Collection

Review Chemistry, Multidisciplinary

Free Radical Chemistry Enabled by Visible Light-Induced Electron Transfer

Daryl Staveness et al.

ACCOUNTS OF CHEMICAL RESEARCH (2016)

Add to Collection

Review Chemistry, Multidisciplinary

Decatungstate Anion for Photocatalyzed Window Ledge Reactions

Davide Ravelli et al.

ACCOUNTS OF CHEMICAL RESEARCH (2016)

Add to Collection

Article Chemistry, Multidisciplinary

Radical Hydrodeiodination of Aryl, Alkenyl, Alkynyl, and Alkyl Iodides with an Alcoholate as Organic Chain Reductant through Electron Catalysis

Abhishek Dewanji et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016)

Add to Collection

Article Chemistry, Multidisciplinary

The Uranyl Cation as a Visible-Light Photocatalyst for C(sp3)-H Fluorination

Julian G. West et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016)

Add to Collection

Article Chemistry, Multidisciplinary

A photoredox catalyzed radical-radical coupling reaction: facile access to multi-substituted nitrogen heterocycles

Weipeng Li et al.

CHEMICAL COMMUNICATIONS (2016)

Add to Collection

Review Chemistry, Multidisciplinary

Dual Catalysis Strategies in Photochemical Synthesis

Kazimer L. Skubi et al.

CHEMICAL REVIEWS (2016)

Add to Collection

Review Chemistry, Multidisciplinary

The medicinal chemist's toolbox for late stage functionalization of drug-like molecules

Tim Cernak et al.

CHEMICAL SOCIETY REVIEWS (2016)

Add to Collection

Article Chemistry, Multidisciplinary

A Light/Ketone/Copper System for Carboxylation of Allylic C-H Bonds of Alkenes with CO2

Naoki Ishida et al.

CHEMISTRY-A EUROPEAN JOURNAL (2016)

Add to Collection

Article Chemistry, Multidisciplinary

Photoorganocatalytic One-Pot Synthesis of Hydroxamic Acids from Aldehydes

Giorgos N. Papadopoulos et al.

CHEMISTRY-A EUROPEAN JOURNAL (2016)

Add to Collection

Article Chemistry, Multidisciplinary

Population of triplet states in acetophenone: A quantum dynamics perspective

Miquel Huix-Rotllant et al.

COMPTES RENDUS CHIMIE (2016)

Add to Collection

Article Chemistry, Organic

Kinetic Study of the Reaction of the Phthalimide-N-oxyl Radical with Amides: Structural and Medium Effects on the Hydrogen Atom Transfer Reactivity and Selectivity

Massimo Bietti et al.

JOURNAL OF ORGANIC CHEMISTRY (2016)

Add to Collection

Article Chemistry, Organic

Fine Control over Site and Substrate Selectivity in Hydrogen Atom Transfer-Based Functionalization of Aliphatic C-H Bonds

Michela Salamone et al.

JOURNAL OF ORGANIC CHEMISTRY (2016)

Add to Collection

Article Chemistry, Organic

One-Pot Amide Bond Formation from Aldehydes and Amines via a Photoorganocatalytic Activation of Aldehydes

Giorgos N. Papadopoulos et al.

JOURNAL OF ORGANIC CHEMISTRY (2016)

Add to Collection

Article Chemistry, Multidisciplinary

Site-Selective Aliphatic C-H Chlorination Using N-Chloroamides Enables a Synthesis of Chlorolissoclimide

Ryan K. Quinn et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2016)

Add to Collection

Article Chemistry, Multidisciplinary

C-H Xanthylation: A Synthetic Platform for Alkane Functionalization

William L. Czaplyski et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2016)

Add to Collection

Article Multidisciplinary Sciences

Asymmetric catalytic formation of quaternary carbons by iminium ion trapping of radicals

John J. Murphy et al.

NATURE (2016)

Add to Collection

Review Chemistry, Organic

Fluorination methods in drug discovery

Damian E. Yerien et al.

ORGANIC & BIOMOLECULAR CHEMISTRY (2016)

Add to Collection

Article Chemistry, Organic

Iron-Catalyzed Oxyfunctionalization of Aliphatic Amines at Remote Benzylic C-H Sites

Curren T. Mbofana et al.

ORGANIC LETTERS (2016)

Add to Collection

Article Chemistry, Organic

Alkylation of Nonacidic C(sp3)-H Bonds by Photoinduced Catalytic Michael-Type Radical Addition

Shin Kamijo et al.

ORGANIC LETTERS (2016)

Add to Collection

Article Chemistry, Organic

Aryl Ketone Catalyzed Radical Allylation of C(sp3)-H Bonds under Photoirradiation

Shin Kamijo et al.

ORGANIC LETTERS (2016)

Add to Collection

Review Chemistry, Applied

Visible Light Photocatalysis: Applications and New Disconnections in the Synthesis of Pharmaceutical Agents

James J. Douglas et al.

ORGANIC PROCESS RESEARCH & DEVELOPMENT (2016)

Add to Collection

Article Multidisciplinary Sciences

Native functionality in triple catalytic cross-coupling: sp3 C-H bonds as latent nucleophiles

Megan H. Shaw et al.

SCIENCE (2016)

Add to Collection

Review Chemistry, Organic

Photochemical Electron and Hydrogen Transfer in Organic Synthesis: The Control of Selectivity

Norbert Hoffmann

SYNTHESIS-STUTTGART (2016)

Add to Collection

Article Chemistry, Organic

Hydrogen atom transfer from tertiary alkanamides to the cumyloxyl radical. The role of substrate structure on alkali and alkaline earth metal ion induced C-H bond deactivation

Michela Salamone et al.

TETRAHEDRON (2016)

Add to Collection

Article Chemistry, Organic

Direct, visible light-sensitized benzylic C-H fluorination of peptides using dibenzosuberenone: selectivity for phenylalanine-like residues

Desta Doro Bume et al.

TETRAHEDRON (2016)

Add to Collection

Article Chemistry, Organic

Visible-light-mediated benzylic sp3 C-H bond functionalization to C-Br or C-N bond

Tianyuan Hou et al.

TETRAHEDRON LETTERS (2016)

Add to Collection

Article Chemistry, Organic

One-pot epoxidation of alkenes using aerobic photoperoxidation of toluenes

Miyabi Taguchi et al.

TETRAHEDRON LETTERS (2016)

Add to Collection

Article Chemistry, Physical

Unraveling the Key Features of the Reactive State of Decatungstate Anion in Hydrogen Atom Transfer (HAT) Photocatalysis

Vincent De Waele et al.

ACS CATALYSIS (2016)

Add to Collection

Article Chemistry, Multidisciplinary

Undirected, Homogeneous C-H Bond Functionalization: Challenges and Opportunities

John F. Hartwig et al.

ACS CENTRAL SCIENCE (2016)

Add to Collection

Article Chemistry, Multidisciplinary

Photoredox Catalysis Unlocks Single-Electron Elementary Steps in Transition Metal Catalyzed Cross-Coupling

Mark D. Levin et al.

ACS CENTRAL SCIENCE (2016)

Add to Collection

Review Chemistry, Multidisciplinary

Tuning Reactivity and Selectivity in Hydrogen Atom Transfer from Aliphatic C-H Bonds to Alkoxyl Radicals: Role of Structural and Medium Effects

Michela Salamone et al.

ACCOUNTS OF CHEMICAL RESEARCH (2015)

Add to Collection

Review Chemistry, Multidisciplinary

Manganese Catalyzed C-H Halogenation

Wei Liu et al.

ACCOUNTS OF CHEMICAL RESEARCH (2015)

Add to Collection

Article Chemistry, Applied

Decatungstate Photocatalyzed Acylations and Alkylations in Flow via Hydrogen Atom Transfer

Filippo Bonassi et al.

ADVANCED SYNTHESIS & CATALYSIS (2015)

Add to Collection

Article Chemistry, Physical

(nBu4N)4W10O32-catalyzed selective oxygenation of cyclohexane by molecular oxygen under visible light irradiation

Wenfeng Wu et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2015)

Add to Collection

Article Chemistry, Physical

Photocatalytic CH Activation by Hydrogen-Atom Transfer in Synthesis

Stefano Protti et al.

CHEMCATCHEM (2015)

Add to Collection

Article Chemistry, Physical

Decatungstate-Photocatalyzed Si-H/C-H Activation in Silyl Hydrides: Hydrosilylation of Electron-Poor Alkenes

Hisham Qrareya et al.

CHEMCATCHEM (2015)

Add to Collection

Article Chemistry, Multidisciplinary

Direct photocatalytic fluorination of benzylic C-H bonds with N-fluorobenzenesulfonimide

Matthew B. Nodwell et al.

CHEMICAL COMMUNICATIONS (2015)

Add to Collection

Article Chemistry, Organic

Photocatalytic One-Pot Synthesis of Homoallyl Ketones via a Norrish Type I Reaction of Cyclopentanones

Megumi Okada et al.

JOURNAL OF ORGANIC CHEMISTRY (2015)

Add to Collection

Article Chemistry, Organic

Enhanced Reactivity in Hydrogen Atom Transfer from Tertiary Sites of Cyclohexanes and Decalins via Strain Release: Equatorial C-H Activation vs Axial C-H Deactivation

Michela Salamone et al.

JOURNAL OF ORGANIC CHEMISTRY (2015)

Add to Collection

Article Chemistry, Organic

Binding to Redox-Inactive Alkali and Alkaline Earth Metal Ions Strongly Deactivates the C-H Bonds of Tertiary Amides toward Hydrogen Atom Transfer to Reactive Oxygen Centered Radicals

Michela Salamone et al.

JOURNAL OF ORGANIC CHEMISTRY (2015)

Add to Collection

Article Chemistry, Organic

Kinetic Solvent Effects on the Reactions of the Cumyloxyl Radical with Tertiary Amides. Control over the Hydrogen Atom Transfer Reactivity and Selectivity through Solvent Polarity and Hydrogen Bonding

Michela Salamone et al.

JOURNAL OF ORGANIC CHEMISTRY (2015)

Add to Collection

Article Chemistry, Organic

Reactivity and Selectivity Patterns in Hydrogen Atom Transfer from Amino Acid C-H Bonds to the Cumyloxyl Radical: Polar Effects as a Rationale for the Preferential Reaction at Proline Residues

Michela Salamone et al.

JOURNAL OF ORGANIC CHEMISTRY (2015)

Add to Collection

Article Chemistry, Multidisciplinary

Platinum-Catalyzed, Terminal-Selective C(sp3)-H Oxidation of Aliphatic Amines

Melissa Lee et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2015)

Add to Collection

Article Chemistry, Multidisciplinary

Remote Oxidation of Aliphatic C-H Bonds in Nitrogen-Containing Molecules

Jennifer M. Howell et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2015)

Add to Collection

Article Multidisciplinary Sciences

Alcohols as alkylating agents in heteroarene C-H functionalization

Jian Jin et al.

NATURE (2015)

Add to Collection

Article Multidisciplinary Sciences

The direct arylation of allylic sp3 C-H bonds via organic and photoredox catalysis

James D. Cuthbertson et al.

NATURE (2015)

Add to Collection

Article Chemistry, Organic

Photocatalyzed Site-Selective C-H to C-C Conversion of Aliphatic Nitriles

Keiichi Yamada et al.

ORGANIC LETTERS (2015)

Add to Collection

Article Chemistry, Organic

Visible-Light-Promoted Conversion of Alkyl Benzyl Ether to Alkyl Ester or Alcohol via O-α-sp3 C-H Cleavage

Ping Lu et al.

ORGANIC LETTERS (2015)

Add to Collection

Article Chemistry, Organic

Development of a Direct Photocatalytic C-H Fluorination for the Preparative Synthesis of Odanacatib

Shira D. Halperin et al.

ORGANIC LETTERS (2015)

Add to Collection

Article Chemistry, Organic

Visible-Light-Driven Photocatalytic Initiation of Radical Thiol-Ene Reactions Using Bismuth Oxide

Olugbeminiyi O. Fadeyi et al.

ORGANIC LETTERS (2015)

Add to Collection

Article Chemistry, Multidisciplinary

Photochemically induced radical reactions with furanones

Michael Oelgemoeller et al.

PURE AND APPLIED CHEMISTRY (2015)

Add to Collection

Article Multidisciplinary Sciences

O-H hydrogen bonding promotes H-atom transfer from α C-H bonds for C-alkylation of alcohols

Jenna L. Jeffrey et al.

SCIENCE (2015)

Add to Collection

Article Chemistry, Organic

Facile and efficient synthesis of hydroxyalkyl esters from cyclic acetals through aerobic photo-oxidation using anthraquinone-2-carboxylic acid

Tomoaki Yamaguchi et al.

TETRAHEDRON LETTERS (2015)

Add to Collection

Article Multidisciplinary Sciences

Acceptorless dehydrogenation of small molecules through cooperative base metal catalysis

Julian G. West et al.

NATURE COMMUNICATIONS (2015)

Add to Collection

Article Chemistry, Multidisciplinary

Aerobic photooxidative direct asymmetric aldol reactions of benzyl alcohols using water as the solvent

A. Fujiya et al.

RSC ADVANCES (2015)

Add to Collection

Article Chemistry, Organic

Electron and hydrogen transfer in organic photochemical reactions

Norbert Hoffmann

JOURNAL OF PHYSICAL ORGANIC CHEMISTRY (2015)

Add to Collection

Review Chemistry, Multidisciplinary

Carbonylation Reactions of Alkyl Iodides through the Interplay of Carbon Radicals and Pd Catalysts

Shuhei Sumino et al.

ACCOUNTS OF CHEMICAL RESEARCH (2014)

Add to Collection

Article Chemistry, Applied

Flow Synthesis of Substituted γ- Lactones by Consecutive Photocatalytic/Reductive Reactions

Maurizio Fagnoni et al.

ADVANCED SYNTHESIS & CATALYSIS (2014)

Add to Collection

Article Chemistry, Applied

Photocatalytic Synthesis of Oxetane Derivatives by Selective C-H Activation

Davide Ravelli et al.

ADVANCED SYNTHESIS & CATALYSIS (2014)

Add to Collection

Article Chemistry, Multidisciplinary

A Convenient Photocatalytic Fluorination of Unactivated C-H Bonds

Shira D. Halperin et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2014)

Add to Collection

Article Chemistry, Multidisciplinary

Excimer Emission in Inclusion Complexes of Dibenzofuran and 5-Dibenzosuberenone with α- and β-Cyclodextrins

Narayanasamy Rajendiran et al.

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN (2014)

Add to Collection

Article Chemistry, Multidisciplinary

C-H nitrogenation and oxygenation by ruthenium catalysis

Vedhagiri S. Thirunavukkarasu et al.

CHEMICAL COMMUNICATIONS (2014)

Add to Collection

Article Chemistry, Multidisciplinary

Visible light-promoted metal-free sp3-C-H fluorination

Ji-Bao Xia et al.

CHEMICAL COMMUNICATIONS (2014)

Add to Collection

Review Chemistry, Multidisciplinary

1,n-Hydrogen-Atom Transfer (HAT) Reactions in Which n ≠ 5: An Updated Inventory

Malek Nechab et al.

CHEMISTRY-A EUROPEAN JOURNAL (2014)

Add to Collection

Article Chemistry, Organic

Hydrogen Atom Transfer from 1,n-Alkanediamines to the Cumyloxyl Radical. Modulating C-H Deactivation Through Acid-Base Interactions and Solvent Effects

Michela Milan et al.

JOURNAL OF ORGANIC CHEMISTRY (2014)

Add to Collection

Article Chemistry, Organic

A Continuous-Flow Protocol for Light-Induced Benzylic Fluorinations

David Cantillo et al.

JOURNAL OF ORGANIC CHEMISTRY (2014)

Add to Collection

Article Chemistry, Multidisciplinary

A General Strategy for Organocatalytic Activation of C-H Bonds via Photoredox Catalysis: Direct Arylation of Benzylic Ethers

Katrine Qvortrup et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2014)

Add to Collection

Article Chemistry, Multidisciplinary

Site-Selective Aliphatic C-H Bromination Using N-Bromoamides and Visible Light

Valerie A. Schmidt et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2014)

Add to Collection

Article Chemistry, Multidisciplinary

Formation of a Room Temperature Stable FeV(O) Complex: Reactivity Toward Unactivated C-H Bonds

Munmun Ghosh et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2014)

Add to Collection

Article Chemistry, Multidisciplinary

Activation of C-H Bonds via the Merger of Photoredox and Organocatalysis: A Coupling of Benzylic Ethers with Schiff Bases

Dominik Hager et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2014)

Add to Collection

Article Chemistry, Organic

Efficient Benzylic and Aliphatic C-H Oxidation with Selectivity for Methylenic Sites Catalyzed by a Bioinspired Manganese Complex

Duyi Shen et al.

ORGANIC LETTERS (2014)

Add to Collection

Article Chemistry, Organic

Proton-Coupled Electron Transfer in Organic Synthesis: Novel Homolytic Bond Activations and Catalytic Asymmetric Reactions with Free Radicals

Hatice G. Yayla et al.

SYNLETT (2014)

Add to Collection

Article Chemistry, Organic

Photocatalytic initiation of thiol-ene reactions: synthesis of thiomorpholin-3-ones

Mitchell H. Keylor et al.

TETRAHEDRON (2014)

Add to Collection

Article Chemistry, Multidisciplinary

Sunlight photocatalyzed regioselective β-alkylation and acylation of cyclopentanones

Megumi Okada et al.

CHEMICAL SCIENCE (2014)

Add to Collection

Article Chemistry, Applied

Decatungstate Photocatalyzed Benzylation of Alkenes with Alkylaromatics

Hisham Qrareya et al.

ADVANCED SYNTHESIS & CATALYSIS (2013)

Add to Collection

Article Chemistry, Multidisciplinary

Site-Selective Oxidation of Unactivated Csp3-H Bonds with Hypervalent Iodine(III) Reagents

Shin A. Moteki et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2013)

Add to Collection

Review Chemistry, Multidisciplinary

Catalytic Functionalization of C(sp2)-H and C(sp3)-H Bonds by Using Bidentate Directing Groups

Guy Rouquet et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2013)

Add to Collection

Review Chemistry, Multidisciplinary

Photoorganocatalysis. What for?

Davide Ravelli et al.

CHEMICAL SOCIETY REVIEWS (2013)

Add to Collection

Article Chemistry, Multidisciplinary

An Iron Catalyst for Oxidation of Alkyl CH Bonds Showing Enhanced Selectivity for Methylenic Sites

Irene Prat et al.

CHEMISTRY-A EUROPEAN JOURNAL (2013)

Add to Collection

Article Chemistry, Organic

Enhanced Reactivity in Dioxirane C-H Oxidations via Strain Release: A Computational and Experimental Study

Lufeng Zou et al.

JOURNAL OF ORGANIC CHEMISTRY (2013)

Add to Collection

Article Chemistry, Multidisciplinary

Effect of Metal Ions on the Reactions of the Cumyloxyl Radical with Hydrogen Atom Donors. Fine Control on Hydrogen Abstraction Reactivity Determined by Lewis Acid-Base Interactions

Michela Salamone et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2013)

Add to Collection

Article Chemistry, Multidisciplinary

Visible Light-Promoted Metal-Free C-H Activation: Diarylketone-Catalyzed Selective Benzylic Mono- and Difluorination

Ji-Bao Xia et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2013)

Add to Collection

Article Chemistry, Multidisciplinary

C-H bond activation enables the rapid construction and late-stage diversification of functional molecules

Joanna Wencel-Delord et al.

NATURE CHEMISTRY (2013)

Add to Collection

Article Chemistry, Physical

Electronic and EPR spectra of the species involved in [W10O32](4-) photocatalysis. A relativistic DFT investigation

Davide Ravelli et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2013)

Add to Collection

Article Chemistry, Organic

Efficient C-H/C-N and C-H/C-CO-N Conversion via Decatungstate-Photoinduced Alkylation of Diisopropyl Azodicarboxylate

Ilhyong Ryu et al.

ORGANIC LETTERS (2013)

Add to Collection

Review Chemistry, Multidisciplinary

Photocatalysis with visible-light-active uranyl complexes

Li Yong et al.

SCIENCE CHINA-CHEMISTRY (2013)

Add to Collection

Article Chemistry, Organic

Photoinduced Direct Cyanation of C(sp3)-H Bonds

Tamaki Hoshikawa et al.

SYNTHESIS-STUTTGART (2013)

Add to Collection

Article Chemistry, Organic

Efficient generation of hydrogen peroxide by aerobic photooxidation of 2-propanol using anthraquinone-2-carboxylic acid and one-pot epoxidation of α,β-unsaturated ketones

Lei Cui et al.

TETRAHEDRON LETTERS (2013)

Add to Collection

Article Chemistry, Organic

Aerobic photooxidative cleavage of 1,3-diketones to carboxylic acids using 2-chloroanthraquinone

Yuma Tachikawa et al.

TETRAHEDRON LETTERS (2013)

Add to Collection

Article Chemistry, Multidisciplinary

Photoinduced direct 4-pyridination of C(sp3)-H Bonds

Tamaki Hoshikawa et al.

CHEMICAL SCIENCE (2013)

Add to Collection

Article Chemistry, Multidisciplinary

Tuning hydrogen atom abstraction from the aliphatic C-H bonds of basic substrates by protonation. Control over selectivity by C-H deactivation

Michela Salamone et al.

CHEMICAL SCIENCE (2013)

Add to Collection

Review Chemistry, Multidisciplinary

PEGylated carbon nanotubes: preparation, properties and applications

Davide Ravelli et al.

RSC ADVANCES (2013)

Add to Collection

Editorial Material Chemistry, Multidisciplinary

C-H Functionalization

Michael P. Doyle et al.

ACCOUNTS OF CHEMICAL RESEARCH (2012)

Add to Collection

Review Chemistry, Multidisciplinary

Controlling Site Selectivity in Palladium-Catalyzed C-H Bond Functionalization

Sharon R. Neufeldt et al.

ACCOUNTS OF CHEMICAL RESEARCH (2012)

Add to Collection

Review Chemistry, Multidisciplinary

Hydrogen-Abstraction Reactivity Patterns from A to Y: The Valence Bond Way

Wenzhen Lai et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2012)

Add to Collection

Article Chemistry, Multidisciplinary

Effects of Alkoxy Substitution on the Optical Properties of 9,10-Anthraquinone and Anthracene: 2,3,6,7-Tetrapropoxy-substituted vs. 2,6-Dipropoxy-substituted Derivatives

Akira Ohta et al.

CHEMISTRY LETTERS (2012)

Add to Collection

Article Chemistry, Organic

Photo-catalysis and Polyoxo-anion Decatungstate in Organic Chemistry: A Manifold Concept for Green Chemistry

Ioannis N. Lykakis et al.

CURRENT ORGANIC CHEMISTRY (2012)

Add to Collection

Article Chemistry, Physical

Perrhenate Complexation by Uranyl in Traditional Solvents and in Ionic Liquids: A Joint Molecular Dynamics/Spectroscopic Study

Alain Chaumont et al.

JOURNAL OF PHYSICAL CHEMISTRY B (2012)

Add to Collection

Article Chemistry, Multidisciplinary

Fluorine Transfer to Alkyl Radicals

Montserrat Rueda-Becerril et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2012)

Add to Collection

Article Chemistry, Organic

Parallel Microflow Photochemistry: Process Optimization, Scale-up, and Library Synthesis

Alexander Yavorskyy et al.

ORGANIC LETTERS (2012)

Add to Collection

Article Biochemistry & Molecular Biology

Direct aerobic photo-oxidative syntheses of aromatic methyl esters from methyl aromatics using anthraquinone-2,3-dicarboxylic acid as organophotocatalyst

Norihiro Tada et al.

PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES (2012)

Add to Collection

Article Polymer Science

Benzophenone-initiated grafting photopolymerization of acrylic acid on the surface of polyethylene from the monomer aqueous solution without its deaeration

O. N. Tretinnikov et al.

POLYMER SCIENCE SERIES B (2012)

Add to Collection

Article Multidisciplinary Sciences

Oxidative Aliphatic C-H Fluorination with Fluoride Ion Catalyzed by a Manganese Porphyrin

Wei Liu et al.

SCIENCE (2012)

Add to Collection

Article Chemistry, Multidisciplinary

Blended hydrogen atom abstraction and proton-coupled electron transfer mechanisms of closed-shell molecules

Chunsen Li et al.

CHEMICAL SCIENCE (2012)

Add to Collection

Article Chemistry, Multidisciplinary

One-Step Decatungstate-Photomediated PEGylation of Single-Walled Carbon Nanotubes

Davide Ravelli et al.

CHEMPLUSCHEM (2012)

Add to Collection

Review Chemistry, Multidisciplinary

Understanding Hydrogen Atom Transfer: From Bond Strengths to Marcus Theory

James M. Mayer

ACCOUNTS OF CHEMICAL RESEARCH (2011)

Add to Collection

Article Chemistry, Applied

A Tin-Free, Radical Photocatalyzed Addition to Vinyl Sulfones

Davide Ravelli et al.

ADVANCED SYNTHESIS & CATALYSIS (2011)

Add to Collection

Review Chemistry, Multidisciplinary

If C-H Bonds Could Talk: Selective C-H Bond Oxidation

Timothy Newhouse et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2011)

Add to Collection

Article Chemistry, Multidisciplinary

Atom-Economical Synthesis of Unsymmetrical Ketones through Photocatalyzed C-H Activation of Alkanes and Coupling with CO and Electrophilic Alkenes

Ilhyong Ryu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2011)

Add to Collection

Editorial Material Chemistry, Multidisciplinary

C-H Functionalization in organic synthesis

Huw M. L. Davies et al.

CHEMICAL SOCIETY REVIEWS (2011)

Add to Collection

Review Chemistry, Multidisciplinary

Recent developments in natural product synthesis using metal-catalysed C-H bond functionalisation

Lindsay McMurray et al.

CHEMICAL SOCIETY REVIEWS (2011)

Add to Collection

Article Chemistry, Multidisciplinary

Smooth Photocatalytic Preparation of 2-Substituted 1,3-Benzodioxoles

Davide Ravelli et al.

CHEMISTRY-A EUROPEAN JOURNAL (2011)

Add to Collection

Article Chemistry, Multidisciplinary

Efficient synthesis of gem-dihydroperoxides with molecular oxygen and anthraquinone under visible light irradiation with fluorescent lamp

Lei Cui et al.

GREEN CHEMISTRY (2011)

Add to Collection

Article Chemistry, Organic

Kinetic Solvent Effects on Hydrogen Abstraction Reactions from Carbon by the Cumyloxyl Radical. The Importance of Solvent Hydrogen-Bond Interactions with the Substrate and the Abstracting Radical

Michela Salamone et al.

JOURNAL OF ORGANIC CHEMISTRY (2011)

Add to Collection

Article Chemistry, Multidisciplinary

Selectivity and Mechanism of Hydrogen Atom Transfer by an Isolable Imidoiron(III) Complex

Ryan E. Cowley et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2011)

Add to Collection

Article Chemistry, Multidisciplinary

Excited State Kinetics in Crystalline Solids: Self-Quenching in Nanocrystals of 4,4′-Disubstituted Benzophenone Triplets Occurs by a Reductive Quenching Mechanism

Gregory Kuzmanich et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2011)

Add to Collection

Article Polymer Science

Decatungstate (W10O324-)/Silane: A New and Promising Radical Source Under Soft Light Irradiation

Jacques Lalevee et al.

MACROMOLECULAR RAPID COMMUNICATIONS (2011)

Add to Collection

Article Chemistry, Organic

Understanding Kinetic Solvent Effects on Hydrogen Abstraction Reactions from Carbon by the Cumyloxyl Radical

Massimo Bietti et al.

ORGANIC LETTERS (2011)

Add to Collection

Article Chemistry, Organic

Photosensitized addition of isopropanol to furanones in a continuous-flow dual capillary microreactor

Alexander Yavorskyy et al.

TETRAHEDRON LETTERS (2011)

Add to Collection

Article Chemistry, Applied

An Efficient Synthesis of gem-Dihydroperoxides with Molecular Oxygen and Anthracene under Light Irradiation

Norihiro Tada et al.

ADVANCED SYNTHESIS & CATALYSIS (2010)

Add to Collection

Article Chemistry, Multidisciplinary

Photochemical Addition of Ethers to C-60: Synthesis of the Simplest [60]Fullerene/Crown Ether Conjugates

Manolis D. Tzirakis et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2010)

Add to Collection

Article Chemistry, Multidisciplinary

Hydroxyalkylation of [60]fullerene: free radical addition of alcohols to C-60

Manolis D. Tzirakis et al.

CHEMICAL COMMUNICATIONS (2010)

Add to Collection

Editorial Material Chemistry, Multidisciplinary

Introduction to Selective Functionalization of C-H Bonds

Robert H. Crabtree

CHEMICAL REVIEWS (2010)

Add to Collection

Review Chemistry, Multidisciplinary

Palladium-Catalyzed Ligand-Directed C-H Functionalization Reactions

Thomas W. Lyons et al.

CHEMICAL REVIEWS (2010)

Add to Collection

Article Chemistry, Inorganic & Nuclear

Matrix effects on the photocatalytic oxidation of alcohols by [nBu(4)N](4)W10O32 incorporated into sol-gel silica

Alessandra Molinari et al.

DALTON TRANSACTIONS (2010)

Add to Collection

Article Chemistry, Physical

Ultrafast Dynamics of the Excited States of the Uranyl Ion in Solutions

Rajib Ghosh et al.

JOURNAL OF PHYSICAL CHEMISTRY A (2010)

Add to Collection

Article Polymer Science

Photoinitiated Polymerization: Advances, Challenges, and Opportunities

Yusuf Yagci et al.

MACROMOLECULES (2010)

Add to Collection

Article Chemistry, Organic

Benzoyl radicals from (hetero)aromatic aldehydes. Decatungstate photocatalyzed synthesis of substituted aromatic ketones

Davide Ravelli et al.

ORGANIC & BIOMOLECULAR CHEMISTRY (2010)

Add to Collection

Article Chemistry, Organic

Kinetic Solvent Effects on Hydrogen Abstraction Reactions from Carbon by the Cumyloxyl Radical. The Role of Hydrogen Bonding

Massimo Bietti et al.

ORGANIC LETTERS (2010)

Add to Collection

Article Biochemistry & Molecular Biology

Photosensitized addition of isopropanol to furanones in a 365 nm UV-LED microchip

Oksana Shvydkiv et al.

PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES (2010)

Add to Collection

Article Multidisciplinary Sciences

Combined Effects on Selectivity in Fe-Catalyzed Methylene Oxidation

Mark S. Chen et al.

SCIENCE (2010)

Add to Collection

Review Chemistry, Multidisciplinary

Cross-Dehydrogenative Coupling (CDC): Exploring C-C Bond Formations beyond Functional Group Transformations

Chao-Jun Li

ACCOUNTS OF CHEMICAL RESEARCH (2009)

Add to Collection

Article Chemistry, Multidisciplinary

Strain Release in C-H Bond Activation?

Ke Chen et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2009)

Add to Collection

Article Chemistry, Multidisciplinary

Stereospecific C-H Oxidation with H2O2 Catalyzed by a Chemically Robust Site-Isolated Iron Catalyst

Laura Gomez et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2009)

Add to Collection

Article Chemistry, Multidisciplinary

Solar light-driven photocatalyzed alkylations. Chemistry on the window ledge

Stefano Protti et al.

CHEMICAL COMMUNICATIONS (2009)

Add to Collection

Review Chemistry, Multidisciplinary

Fullerene for organic electronics

Dirk M. Guldi et al.

CHEMICAL SOCIETY REVIEWS (2009)

Add to Collection

Review Chemistry, Multidisciplinary

Decatungstate as an efficient photocatalyst in organic chemistry

Manolis D. Tzirakis et al.

CHEMICAL SOCIETY REVIEWS (2009)

Add to Collection

Review Chemistry, Multidisciplinary

Photocatalysis. A multi-faceted concept for green chemistry

Davide Ravelli et al.

CHEMICAL SOCIETY REVIEWS (2009)

Add to Collection

Article Chemistry, Multidisciplinary

Regio- and Stereoselectivity in the Decatungstate Photocatalyzed Alkylation of Alkenes by Alkylcyclohexanes

Daniele Dondi et al.

CHEMISTRY-A EUROPEAN JOURNAL (2009)

Add to Collection

Article Chemistry, Organic

Decatungstate-Catalyzed Photooxygenation of S-2-Phenylbutane and Cumene via a Free Carbon-Radical Intermediate

Ioannis N. Lykakis et al.

CURRENT ORGANIC CHEMISTRY (2009)

Add to Collection

Article Chemistry, Multidisciplinary

Synthesis of gamma-lactols, gamma-lactones and 1,4-monoprotected succinaldehydes under moderately concentrated sunlight

Daniele Dondi et al.

GREEN CHEMISTRY (2009)

Add to Collection

Article Chemistry, Physical

Synthesis of electron-accepting polymers containing phenanthra-9,10-quinone units

Julien E. Gautrot et al.

JOURNAL OF MATERIALS CHEMISTRY (2009)

Add to Collection

Article Chemistry, Physical

A combined laser flash photolysis, density functional theory and atoms in molecules study of the photochemical hydrogen abstraction by pyrene-4,5-dione

Nanci C. de Lucas et al.

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY (2009)

Add to Collection

Article Chemistry, Multidisciplinary

Acyl Radical Reactions in Fullerene Chemistry: Direct Acylation of [60]Fullerene through an Efficient Decatungstate-Photomediated Approach

Manolis D. Tzirakis et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2009)

Add to Collection

Article Multidisciplinary Sciences

Total synthesis of eudesmane terpenes by site-selective C-H oxidations

Ke Chen et al.

NATURE (2009)

Add to Collection

Article Chemistry, Organic

The reaction of photochemically generated α-hydroxyalkyl radicals with alkynes: a synthetic route to γ-butenolides

Niall W. A. Geraghty et al.

TETRAHEDRON LETTERS (2009)

Add to Collection

Review Chemistry, Multidisciplinary

Function-oriented synthesis, step economy, and drug design

Paul A. Wender et al.

ACCOUNTS OF CHEMICAL RESEARCH (2008)

Add to Collection

Article Chemistry, Applied

Tetrabutylammonium Decatungstate (Chemo)selective Photocatalyzed, Radical C-H Functionalization in Amides

Simone Angioni et al.

ADVANCED SYNTHESIS & CATALYSIS (2008)

Add to Collection

Review Chemistry, Multidisciplinary

Organic photovoltaics - Polymer-fullerene composite solar cells

Barry C. Thompson et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2008)

Add to Collection

Article Chemistry, Physical

Selective photooxidation of diols with silica bound W10O324-

A. Maldotti et al.

JOURNAL OF CATALYSIS (2008)

Add to Collection

Article Chemistry, Organic

Decatungstate-mediated radical reactions of C60 with substituted toluenes and anisoles:: A new photochemical functionalization strategy for fullerenes

Manolis D. Tzirakis et al.

ORGANIC LETTERS (2008)

Add to Collection

Article Chemistry, Physical

Observation of a novel emission from an exciplex of triplet 4-phenylbenzophenone with triethylamine

Shun-Chi Chen et al.

CHEMICAL PHYSICS LETTERS (2007)

Add to Collection

Article Chemistry, Physical

Decatungstate catalyst supported on silica and γ-alumina:: Efficient photocatalytic oxidation of benzyl alcohols

Manolis D. Tzirakis et al.

JOURNAL OF CATALYSIS (2007)

Add to Collection

Article Chemistry, Physical

Zirconia-supported sodium decatungstate (Na4W10O32/ZrO2):: An efficient, green and recyclable photocatalyst for selective oxidation of activated alcohols to carbonyl compounds with O2

Saeid Farhadi et al.

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL (2007)

Add to Collection

Article Multidisciplinary Sciences

A predictably selective aliphatic C-H oxidation reaction for complex molecule synthesis

Mark S. Chen et al.

SCIENCE (2007)

Add to Collection

Article Chemistry, Organic

Electrophilicity and nucleophilicity index for radicals

Freija De Vleeschouwer et al.

ORGANIC LETTERS (2007)

Add to Collection

Review Chemistry, Multidisciplinary

High-valent iron(IV)-oxo complexes of heme and non-heme ligands in oxygenation reactions

Wonwoo Nam

ACCOUNTS OF CHEMICAL RESEARCH (2007)

Add to Collection

Review Chemistry, Multidisciplinary

Photocatalysis for the formation of the C-C bond

Maurizio Fagnoni et al.

CHEMICAL REVIEWS (2007)

Add to Collection

Article Chemistry, Physical

Photocatalyzed oxidation of cyclohexane with heterogenized decatungstate

Emilia Fornal et al.

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY (2007)

Add to Collection

Article Chemistry, Physical

Acetone, a substrate and a new solvent in decatungstate photocatalysis

Charles Tanielian et al.

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL (2007)

Add to Collection

Article Chemistry, Physical

Mechanism of decatungstate photocatalyzed oxygenation of aromatic alcohols Part I. Continuous photolysis and laser flash photolysis studies

Charles Tanielian et al.

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL (2007)

Add to Collection

Article Chemistry, Physical

Mechanism of decatungstate photocatalyzed oxygenation of aromatic alcohols Part II. Kinetic isotope effects studies

Ioannis N. Lykakis et al.

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL (2007)

Add to Collection

Review Chemistry, Multidisciplinary

Photocatalysis: a promising route for 21st century organic chemistry

Giovanni Palmisano et al.

CHEMICAL COMMUNICATIONS (2007)

Add to Collection

Review Chemistry, Multidisciplinary

Fullerenes: Multitask components in molecular machinery

Aurelio Mateo-Alonso et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2007)

Add to Collection

Article Chemistry, Multidisciplinary

Acylation of electrophilic olefins through decatungstate-photocatalyzed activation of aldehydes

Silvia Esposti et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2007)

Add to Collection

Article Chemistry, Organic

Homogeneous decatungstate-catalyzed photooxygenation of tetrasubstituted alkenes: A deuterium kinetic isotope effect study

Ioannis N. Lykakis et al.

JOURNAL OF ORGANIC CHEMISTRY (2006)

Add to Collection

Article Chemistry, Multidisciplinary

Dependence of the thioxanthone triplet-triplet absorption spectrum with solvent polarity and aromatic ring substitution

Giovana C. Ferreira et al.

JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY (2006)

Add to Collection

Article Chemistry, Organic

Photomediated synthesis of β-alkylketones from cycloalkanes

Daniele Dondi et al.

TETRAHEDRON (2006)

Add to Collection

Article Chemistry, Multidisciplinary

Tetrabutylammonium decatungstate-photosensitized alkylation of electrophilic alkenes: Convenient functionalization of aliphatic C-H bonds

Daniele Dondi et al.

CHEMISTRY-A EUROPEAN JOURNAL (2006)

Add to Collection

Article Chemistry, Organic

Diaryl ketones as photoactivators

J Pérez-Prieto et al.

MINI-REVIEWS IN ORGANIC CHEMISTRY (2006)

Add to Collection

Article Chemistry, Organic

The photomediated reaction of alkynes with cycloalkanes

RA Doohan et al.

ORGANIC & BIOMOLECULAR CHEMISTRY (2006)

Add to Collection

Article Chemistry, Multidisciplinary

Solvent-free, heterogeneous photooxygenation of hydrocarbons by Hyflon (R) membranes embedding a fluorous-tagged decatungstate

Mauro Carraro et al.

CHEMICAL COMMUNICATIONS (2006)

Add to Collection

Review Chemistry, Physical

Antimony porphyrin complexes as visible-light driven photocatalyst

T Shiragami et al.

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY C-PHOTOCHEMISTRY REVIEWS (2005)

Add to Collection

Article Chemistry, Organic

Deuterium kinetic isotope effects in homogeneous decatungstate catalyzed photooxygenation of 1,1-diphenylethane and 9-methyl-9H-fluorene:: evidence for a hydrogen abstraction mechanism

IN Lykakis et al.

TETRAHEDRON LETTERS (2005)

Add to Collection

Article Chemistry, Inorganic & Nuclear

Mesoporous silica-supported uranyl: synthesis and photoreactivity

JA Nieweg et al.

INORGANIC CHEMISTRY (2005)

Add to Collection

Article Chemistry, Physical

Autoxidation of cyclohexane: Conventional views challenged by theory and experiment

I Hermans et al.

CHEMPHYSCHEM (2005)

Add to Collection

Article Chemistry, Multidisciplinary

A comparative analysis of the functionalisation of unactivated cycloalkanes using alkynes and either sunlight or a photochemical reactor

RA Doohan et al.

GREEN CHEMISTRY (2005)

Add to Collection

Article Chemistry, Multidisciplinary

Polyoxotungstate photoinduced alkylation of electrophilic alkenes by cycloalkanes

D Dondi et al.

CHEMISTRY-A EUROPEAN JOURNAL (2004)

Add to Collection

Article Chemistry, Organic

Stereoselective photochemical 1,3-dioxolane addition to 5-alkoxymethyl-2(5H)-furanone:: Synthesis of bis-tetrahydrofuranyl ligand for HIV protease inhibitor UEC-94017 (TMC-114)

AK Ghosh et al.

JOURNAL OF ORGANIC CHEMISTRY (2004)

Add to Collection

Article Spectroscopy

Photophysical studies of 9,10-phenanthrenequinones

DM Togashi et al.

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY (2004)

Add to Collection

Review Chemistry, Organic

Reactions of δ-carbon radicals generated by 1,5-hydrogen transfer to alkoxyl radicals

Z Cekovic

TETRAHEDRON (2003)

Add to Collection

Article Chemistry, Organic

Oxyfunctionalization of non-natural targets by dioxiranes. 5. Selective oxidation of hydrocarbons bearing cyclopropyl moieties

L D'Accolti et al.

JOURNAL OF ORGANIC CHEMISTRY (2003)

Add to Collection

Review Chemistry, Multidisciplinary

Oxidation of C-H bonds by [(bpy)2(py)RuIVO]2+ occurs by hydrogen atom abstraction

JR Bryant et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2003)

Add to Collection

Article Chemistry, Organic

Decatungstate photocatalyzed oxidation of aryl alkanols. Electron transfer or hydrogen abstraction mechanism?

IN Lykakis et al.

ORGANIC LETTERS (2003)

Add to Collection

Article Chemistry, Physical

Solvent polarity at polar solid surfaces: The role of solvent structure

XY Zhang et al.

JOURNAL OF PHYSICAL CHEMISTRY B (2003)

Add to Collection

Article Biochemistry & Molecular Biology

Polyoxometalate sensitization in mechanistic studies of photochemical reactions: The decatungstate anion as a reference sensitizer for photoinduced free radical oxygenations of organic compounds

Charles Tanielian et al.

PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES (2003)

Add to Collection

Article Chemistry, Organic

A convenient route to 1,4-monoprotected dialdehydes, 1,4-ketoaldehydes, γ-lactols and γ-lactones through radical alkylation of α,β-unsaturated aldehydes in organic and organic-aqueous media

D Dondi et al.

TETRAHEDRON (2003)

Add to Collection

Review Chemistry, Multidisciplinary

Functionalized fullerenes in water. The first 10 years of their chemistry, biology, and nanoscience

E Nakamura et al.

ACCOUNTS OF CHEMICAL RESEARCH (2003)

Add to Collection

Article Chemistry, Inorganic & Nuclear

Complexation of U(VI) with iodate ions: determination of stability constants by using spectroscopic methods and capillary zone electrophoresis

M Karbowiak et al.

RADIOCHIMICA ACTA (2003)

Add to Collection

Article Chemistry, Multidisciplinary

Tetralkylammonium and sodium decatungstate heterogenized on silica: Effects of the nature of cations on the photocatalytic oxidation of organic substrates

A Molinari et al.

LANGMUIR (2002)

Add to Collection

Article Chemistry, Physical

Immobilization of (n-Bu4N)4W10O32 on mesoporous MCM-41 and amorphous silicas for photocatalytic oxidation of cycloalkanes with molecular oxygen

A Maldotti et al.

JOURNAL OF CATALYSIS (2002)

Add to Collection

Review Chemistry, Multidisciplinary

Selective alkane transformations via radicals and radical cations: Insights into the activation step from experiment and theory

AA Fokin et al.

CHEMICAL REVIEWS (2002)

Add to Collection

Article Chemistry, Multidisciplinary

A comparative photomechanistic study (spin trapping, EPR spectroscopy, transient kinetics, photoproducts) of nucleoside oxidation (dG and 8-oxodG) by triplet-excited acetophenones and by the radicals generated from α-oxy-substituted derivatives through Norrish-Type I cleavage

W Adam et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2002)

Add to Collection

Article Chemistry, Organic

Hydrocarbon activation.: Synthesis of β-cycloalkyl (Di)nitriles through photosensitized conjugate radical addition

AM Cardarelli et al.

JOURNAL OF ORGANIC CHEMISTRY (2001)

Add to Collection

Review Chemistry, Inorganic & Nuclear

Alkane C-H activation and functionalization with homogeneous transition metal catalysts: a century of progress-a new millennium in prospect

RH Crabtree

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS (2001)

Add to Collection

Article Chemistry, Multidisciplinary

Influence of remote substituents on the equatorial/axial selectivity in the monooxygenation of methylene C-H bonds of substituted cyclohexanes

ME González-Núñez et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2001)

Add to Collection

Article Chemistry, Organic

Functionalisation of cycloalkanes: the photomediated reaction of cycloalkanes with alkynes

NWA Geraghty et al.

TETRAHEDRON LETTERS (2001)

Add to Collection

Article Chemistry, Physical

Does molecular size matter in photoinduced electron transfer reactions?

C Serpa et al.

JOURNAL OF PHYSICAL CHEMISTRY A (2000)

Add to Collection

Article Chemistry, Multidisciplinary

Photochemical reactions of coenzyme PQQ (Pyrroloquinolinequinone) and analogues with benzyl alcohol derivatives via photoinduced electron transfer

S Fukuzumi et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2000)

Add to Collection

Article Spectroscopy

Photophysical properties of 5H-dibenzo(a,d)cyclohepten-5-one in different solutions

E Kavlakoglu et al.

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY (2000)

Add to Collection

Article Chemistry, Physical

Reactivity of the charge transfer excited state of sodium decatungstate at the nanosecond time scale

I Texier et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2000)

Add to Collection

Direct Photocatalyzed Hydrogen Atom Transfer (HAT) for Aliphatic C-H Bonds Elaboration

Related references