4.7 Article

Multi-functional silk fibers/fabrics with a negligible impact on comfortable and wearability properties for fiber bulk

Journal

CHEMICAL ENGINEERING JOURNAL
Volume 415, Issue -, Pages -

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2021.128980

Keywords

Silk fibers/fabrics; Amorphous TiO2; Anti-UV/yellowing; Thermal management

Funding

  1. National Natural Science Foundation of China [52073082, 51773158, 51903008]
  2. Key Program for Intergovernmental S&T Innovation Cooperation Projects of the National Key R&D Program of China [2019YFE0107100]
  3. China Postdoctoral Science Foundation [2018 M640042, 2020 T130036]
  4. Natural Science Foundation of Hubei Province [2017CFB489]
  5. Open Foundation of Ministry of Education Key Laboratory for the Green Preparation and Application of Functional Materials from Hubei University [2019-3]
  6. Open Foundation of State Key Laboratory of BioFibers from Qingdao University [KF2020105]

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An ultra-thin amorphous titanium dioxide nano-film prepared on the surface of silk fibers/fabrics using atomic layer deposition (ALD) methods can improve the photostability of silk, maintain its comfort, and exhibit excellent UV resistance.
As a luxurious textile for more than five thousand years, silk fibers/products have always been favored by consumers and the markets, but the poor photostability seriously hinders its utilization in fashionable apparel. Even if enduing the functionality of silk fiber through surface modification, it is often at the expense of its comfort. Here, an ultra-thin amorphous titanium dioxide nano-film with a thickness of only five in a thousand of fiber diameter and the add-on percentage <= 5.33% was prepared on the surface of silk fibers/fabrics by atomic layer deposition (ALD) methods. The tensile strength of the modified silk fiber maintains 89.17% of the original fiber after exposure to UV light for 672 h. They can also withstand multi-cycle laundering and accelerate light-aging, which exhibiting an excellent UV resistance. Most importantly, the functional coating has a negligible impact on the comfortable and wearability performance of silk fibers/fabrics. In addition, ALD-coated silk fabric is also further used as an outdoor reflective cooling material and achieving a superior thermal insulation effect with the temperature reduction up to 10.1 degrees C.

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