Journal
CHEMCATCHEM
Volume 13, Issue 16, Pages 3594-3600Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cctc.202100654
Keywords
heterogeneous catalyst; V2O5@TiO2; carbonyls; selective oxygenation; oxidative scission
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Funding
- Council of Scientific and Industrial Research (CSIR), New Delhi under CSIR-INPROTICS-Pharma and Agro mission project [HCP0011]
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The study reported a reusable heterogeneous V2O5@TiO2 catalyzed selective oxidation method, utilizing different mild and eco-friendly oxidants under greener reaction conditions to oxidize various functionalities.
The versatile application of different functional groups such as alcohols (1 degrees and 2 degrees), alkyl arenes, and (aryl)olefins to construct carbon-oxygen bond via oxidation is an area of intense research. Here, we report a reusable heterogeneous V2O5@TiO2 catalyzed selective oxidation of various functionalities utilizing different mild and eco-compatible oxidants under greener reaction conditions. The method was successfully applied for the alcohol oxidation, oxidative scission of styrenes, and benzylic C-H oxidation to their corresponding aldehydes and ketones. The utilization of mild and eco-friendly oxidizing reagents such as K2S2O8, H2O2 (30 % aq.), TBHP (70 % aq.), broad substrate scope, gram-scale synthesis, and catalyst recyclability are notable features of the developed protocol.
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