Effect of Al atomic layer on the wetting behavior, interface structure and electrical contact properties of silver reinforced by Ti3AlC2 ceramic

Ti3AlC2 ceramic exhibits potential in Ag-based composite electrical contact materials, but its interface characteristic with Ag matrix remains unexplored. In this work, sessile drop experiment is carried out to investigate the high-temperature wetting behavior of molten Ag with Ti3AlC2. Stable Ti3AlC2 is hardly wetted by molten Ag below 1000 degrees C(contact angle of 148.5 degrees), but the wettability of Ag/Ti3AlC2 improves with the increasing temperature(final 14 degrees at similar to 1130 degrees C). In contrast, the Ti3C2, a MXene with Al layer removed from its parent Ti3AlC2, exhibits inferior wettability with Ag(final 56.5 degrees at similar to 1130 degrees C). Wetting mechanism of Ag/Ti3AlC2 is proposed on the basis of the interfacial structure and chemical composition. Increasing temperature accelerates dissociation of Ti3AlC2, and outward-escaping Al reacts with Ag to form interface layer with a composition of Ag4.86Ti8.66AlC7.59, Ag also diffuses along Ti3AlC2 grain boundaries and forms gradient reactive products (Ag-Ti-Al-C), which promotes their wettability. Finally comprehensive properties of Ag/Ti3AlC2 and Ag/Ti3C2 are compared. Al-Ag interdiffusion slightly decreases the electrical conductivity of Ag/Ti3AlC2 bulk material, but strengthen the interface bonding of composite and promote the viscosity of the molten pool, leading to the superior mechanical and anti-arc erosion properties. Absence of Al-Ag interdiffusion does remarkably improve the electrical conductivity of Ag/Ti3C2 bulk materials, but lack of Al layer damages the mechanical core and wettability with Ag, resulting in a drastic decrease of anti-arco erosion property.

Automated summary

Ti3AlC2 ceramic shows potential in Ag-based composite electrical contact materials, with wetting behavior improving at higher temperatures. The wetting mechanism of Ag/Ti3AlC2 is proposed based on interfacial structure and chemical composition, with Al-Ag interdiffusion enhancing interface bonding and mechanical properties. On the other hand, absence of Al layer in Ti3C2 results in poor wetting and decreased anti-arc erosion properties with Ag.