4.8 Article

Flash graphene from rubber waste

Journal

CARBON
Volume 178, Issue -, Pages 649-656

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.carbon.2021.03.020

Keywords

Flash graphene; Rubber waste; Turbostratic graphene; Upcycling; Flash joule heating

Funding

  1. Air Force Office of Scientific Research [FA9550-19-1-0296]
  2. DOE-NETL [DE-FE0031794]

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This study demonstrates the optimization of producing graphene from rubber waste using flash Joule heating (FJH), resulting in turbostratic graphene with unique structural arrangements that can be easily dispersed and enhance the compressive strength of cement composites. FJH provides a facile and inexpensive method for upcycling low-value rubber waste into high-value carbon nanomaterials as reinforcing additives.
Most conventional production processes for graphene are time-consuming, solvent-intensive, and energetically demanding. To circumvent these limitations for mass production, flash Joule heating (FJH) has been shown to be an effective method to synthesize graphene. Here, methods for optimizing production of graphene from rubber waste feedstocks are shown. Through careful control of system parameters, such as pulse voltage and pulse time, turbostratic flash graphene (tFG) can be produced from rubber waste. It is characterized by Raman spectroscopy, X-ray diffraction and thermogravimetric analysis. The resulting tFG can be easily exfoliated and dispersed into various solvents because of its turbostratic arrangement. Addition of tFG into Portland cement results in a significant increase in the compressive strength of the composite. From a materials perspective, FJH offers a facile and inexpensive method for producing high quality tFG from rubber waste materials, which would otherwise be disposed of in landfills or burned for fuel. FJH allows for upcycling of low-value rubber waste into high-value carbon nanomaterials for use as reinforcing additives. (C) 2021 Elsevier Ltd. All rights reserved.

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