In-situ growth of single-crystal plasmonic aluminum-lithium-graphene nanosheets with a hexagonal platelet-like morphology using ball-milling

Metal-graphene nanocomposites and plasmonic metal nanoparticles are two nanoscience fields of a rapidly growing interest due to their potential in advanced applications. In this study, we combine both fields by synthesizing plasmonic aluminum-lithium-graphene nanosheets (Al-Li-GNSs) with anisotropic morphologies using a simple ball-milling technique. Structural analysis using SEM and TEM revealed that the Al-Li-GNSs nanoparticles are single-crystals with a hexagonal platelet-like morphology of a similar to 300-500 nm diagonal and a similar to 60 nm thickness. Electron diffraction analysis indicated that the as-milled platelets have an FCC structure with (111) top and bottom facets and revealed the presence of 1/3(422) and 1/3(220) forbidden reflections. UV-Vis spectroscopy of the hexagonal Al-based nanoplatelets was found to exhibit plasmonic resonance absorption bands in the UV region at a wavelength of 214 nm and 345 nm. In this report, we confirm the feasibility of building epitaxial plasmonic metal-graphene systems inside bulk metal-graphene composites using a simple milling process. (C) 2021 The Author(s). Published by Elsevier Ltd.

Automated summary

Metal-graphene nanocomposites and plasmonic metal nanoparticles are two rapidly growing nanoscience fields with potential in advanced applications. This study synthesizes plasmonic aluminum-lithium-graphene nanosheets with anisotropic morphologies and confirms the feasibility of building epitaxial plasmonic metal-graphene systems inside bulk metal-graphene composites using a simple milling process. The hexagonal Al-based nanoplatelets exhibit plasmonic resonance absorption bands in the UV region.