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Robust Gels Composed of Self-Assembled Cello-oligosaccharide Networks

Journal

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
Volume 94, Issue 9, Pages 2279-2289

Publisher

CHEMICAL SOC JAPAN
DOI: 10.1246/bcsj.20210234

Keywords

Cello-oligosaccharide; Self-assembly; Gel

Funding

  1. JSPS KAKENHI [JP21K14688, JP21H01996]
  2. MEXT KAKENHI [JP20H05208]

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Dynamic properties are not essential to molecular assemblies, and statically assembled molecular gels also have unique applications.
Assembled molecular gels exhibit dynamic properties and have been developed as functional soft materials with self-healing ability, stimuli responsiveness, and other such properties. Nevertheless, dynamicity is not essential to molecular assemblies. We created static and robust hydrogels composed of self-assembled cello-oligosaccharide networks. In fact, the novel gels are solvent-exchangeable from water even to nonpolar organic solvents, reflecting extremely low stimuli responsiveness. This Account summarizes our recent research progress on cello-oligosaccharide gels, from their production to applications that exploit the unique properties of these crystalline oligosaccharide assemblies. Our findings suggest that statically assembled molecular gels have unconventional applications.

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