4.7 Article

MnO2 nanoshells/Ti3C2Tx MXene hybrid film as supercapacitor electrode

Journal

APPLIED SURFACE SCIENCE
Volume 560, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.apsusc.2021.150040

Keywords

Ti3C2Tx MXene; MnO2 nanoshells; Porous structure; Pseudo-capacitance; Supercapacitor

Funding

  1. National Natural Science Foundation of China [51572031]
  2. Innovation Project of Qian Xuesen Laboratory of China Academy of Space Technology

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The flexible MnO2/Ti3C2Tx hybrid film, with its unique porous structure, significantly improved the specific surface area, specific capacitance, and cycle stability compared to MnO2 nanoshells and porous Ti3C2Tx nanosheets.
A flexible MnO2/Ti3C2Tx hybrid film was prepared and used directly as pseudo-capacitive electrode for supercapacitors, composed of alternately arranged porous Ti3C2Tx nanosheets and MnO2 nanoshells. The unique porous structure of the film facilitated the ion transport both in the vertical and in-plane directions by the nanopores in the intra-layer and inter-layer of Ti3C2Tx nanosheets. And the specific surface area, specific capacitance and cycle stability of the hybrid film were dramatically improved compared with those of MnO2 nanoshells and porous Ti3C2Tx nanosheets.

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