Nonlinear variation of resonant frequency with temperature and temperature-dependent τf in Al2O3-TiO2 microwave dielectric composites

The temperature coefficient of resonant frequency (tau (f)) is a key parameter for microwave dielectric ceramics, and it is usually regarded as a temperature-independent constant over a wide temperature range. However, the present theoretical prediction shows that the resonant frequency (f(0)) first increases then decreases with temperature, and tau (f) decreases monotonously in Al2O3-TiO2 composite with small tau (f), which fits the experimental data very well. The nonlinear variation of f(0) with temperature and temperature-dependent tau (f) are attributed to the temperature-sensitive permittivity (epsilon (r)) and tau (f) of the constituting phases and also dependent on the dielectric mixing rule that the composite obeys. Such temperature-dependent dielectric behaviors are predicted to be common in microwave dielectric composites with small tau (f), and the negligence of them probably conceals the real large variation of f(0) with temperature and seriously misleads the practical applications. Therefore, it is strongly suggested to understand the real temperature dependence of f(0) and tau (f) in microwave dielectric composites by measuring f(0) at more temperatures with a smaller interval, so that the central frequency shift can be correctly evaluated for the resonator units and devices where the microwave dielectric composites are utilized. Furthermore, the nonlinear variation of f(0) with temperature and temperature dependence of tau (f) are expected to be suppressed by microstructural engineering and adopting more suitable constituting phases.

Automated summary

The temperature coefficient of resonant frequency in microwave dielectric ceramics is not constant and depends on the permittivity of constituting phases and mixing rules. It is crucial to measure resonant frequency at more temperatures to accurately evaluate frequency shifts in practical applications. Engineering microstructures and adopting suitable phases can potentially suppress the temperature-dependent behavior of resonant frequency and coefficient.