Journal
APPLIED ORGANOMETALLIC CHEMISTRY
Volume 35, Issue 11, Pages -Publisher
WILEY
DOI: 10.1002/aoc.6398
Keywords
battery-type supercapacitor; ferrocene; porous organic polymer
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Funding
- University of Tabriz [SAD/1808-990701]
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The research focused on the preparation of redox-active porous polymers and composite materials with high specific capacitance and excellent charge storage retention, using a cost-effective synthetic route.
Redox-active porous polymers are promising electrode materials due to various advantages including high specific surface area and porosity, facile synthesizing route, and excellent chemical and thermal stability. Herein, a simple and cost-effective Schiff base reaction was used to prepare the ferrocene (Fc) containing porous organic polymer (POP) through the formation of a C-N bond between melamine and 1,1 '-diacetylferrocene. After successful preparation of the Fc-POP, Fc-POP/PANI nanohybrid was prepared by the hybridization of synthesized redox-active polymer with polyaniline (PANI) as a conductive polymer. Finally, the CNT (carbon nanotube)-containing nanocomposites were prepared by adding various amounts of the CNT to Fc-POP/PANI nanohybrid. All as-prepared electrode materials were thoroughly characterized with usual analyses. The Fc-POP/PANI/CNT20 revealed a high specific capacitance of 494 mAh g(-1) at 2.5 A g(-1) and excellent charge storage retention (92.1%) over 5000 cycles. Also, the fabricated symmetric cell exhibits a high energy density of 76 W h kg(-1) and a high-power density of 5840 W kg(-1).
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