Influence of micro-nano surface texture on the hydrophobicity and corrosion resistance of a Ti6Al4V alloy surface

Purpose The purpose of this paper is to study the effect of micro-nano surface texture on the corrosion resistance of a titanium alloy and investigate the correlation between corrosion resistance and hydrophobicity. Design/methodology/approach The surface of the Ti6Al4V alloy was modified by laser processing and anodizing to fabricate micro-pits, nanotubes and micro-nano surface textures. Afterward, the surface morphology, hydrophobicity and polarization curve of the samples were analyzed by cold field scanning electron microscopy, contact angle measurement instruments and a multi-channel electrochemical workstation. Findings The micro-nano surface texture can enhance the hydrophobicity of the Ti6Al4V surface, which may lead to better drag reduction to ease the friction of implants in vivo. Nevertheless, no correlation existed between surface hydrophobicity and corrosion resistance; the corrosion resistance of samples with nanotubes and high-density samples with micro-nano surface texture was extremely enhanced, indicating the similar corrosion resistance of the two. Research limitations/implications The mechanism of micro-dimples on the corrosion resistance of the micro-nano surface texture was not studied. Practical implications The density of micro-pits needs to be optimized to guarantee excellent corrosion resistance in the design of the micro-nano surface texture; otherwise, it will not fulfill the requirement of surface modification. Originality/value The influence of the micro-nano surface texture on the corrosion resistance, as well as the relationship between hydrophobicity and corrosion resistance of the titanium alloy surface, were systematically investigated for the first time. These conclusions offer new knowledge.

Automated summary

The micro-nano surface texture can enhance the hydrophobicity of the Ti6Al4V surface, potentially reducing friction of implants in vivo. However, surface hydrophobicity did not correlate with corrosion resistance; samples with nanotubes and high-density micro-nano surface texture showed significantly improved corrosion resistance, indicating similar performance.