A Heteromeric Carboxylic Acid Based Single-Crystalline Crosslinked Organic Framework

The development of large pore single-crystalline covalently linked organic frameworks is critical in revealing the detailed structure-property relationship with substrates. One emergent approach is to photo-crosslink hydrogen-bonded molecular crystals. Introducing complementary hydrogen-bonded carboxylic acid building blocks is promising to construct large pore networks, but these molecules often form interpenetrated networks or non-porous solids. Herein, we introduced heteromeric carboxylic acid dimers to construct a non-interpenetrated molecular crystal. Crosslinking this crystal precursor with dithiols afforded a large pore single-crystalline hydrogen-bonded crosslinked organic framework HCOF-101. X-ray diffraction analysis revealed HCOF-101 as an interlayer connected hexagonal network, which possesses flexible linkages and large porous channels to host a hydrazone photoswitch. Multicycle Z/E-isomerization of the hydrazone took place reversibly within HCOF-101, showcasing the potential use of HCOF-101 for optical information storage.

Automated summary

The study introduced heteromeric carboxylic acid dimers to construct a non-interpenetrated hydrogen-bonded crosslinked organic framework, HCOF-101, which was shown through X-ray diffraction analysis to possess large porous channels suitable for hosting a hydrazone photoswitch. Multicycle Z/E-isomerization of the hydrazone within HCOF-101 demonstrated the potential use of HCOF-101 for optical information storage.