4.8 Article

Regio-controllable Cobalt-Catalyzed Sequential Hydrosilylation/Hydroboration of Arylacetylenes

Related references

Note: Only part of the references are listed.
Article Chemistry, Multidisciplinary

Chiral Imidazoline Ligands and Their Applications in Metal-Catalyzed Asymmetric Synthesis†

Jiajing Li et al.

Summary: Imidazoline, as a structural analog of oxazoline, has gained significant attention in the rational design of chiral ligands due to its additional N-substituent allowing for fine-tuning of electronic and steric effects. Various chiral imidazoline ligands have been designed and employed in asymmetric organic reactions, expanding the applications of chiral synthesis.

CHINESE JOURNAL OF CHEMISTRY (2021)

Article Chemistry, Multidisciplinary

sp3 Bis-Organometallic Reagents via Catalytic 1,1-Difunctionalization of Unactivated Olefins

Shang-Zheng Sun et al.

Summary: A catalytic 1,1-difunctionalization of unactivated olefins is described for the synthesis of sp(3) bis-organometallic B,B(Si)-reagents. The protocol features exceptional reaction rates, mild conditions, wide scope, and exquisite selectivity pattern, providing a new platform for accessing sp(3) bis-organometallics.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Review Chemistry, Multidisciplinary

Iron- and Cobalt-Catalyzed Asymmetric Hydrofunctionalization of Alkenes and Alkynes

Jun Guo et al.

Summary: Transition metal-catalyzed asymmetric hydro-functionalization has been a straightforward and atom-economic way to access valuable optically active products. While noble transition metals have dominated this field, the attention has recently shifted to first-row, earth-abundant transition metals for their economic and sustainable advantages. However, the limited availability of chiral ligand libraries remains a significant challenge in developing highly enantioselective versions for these earth-abundant metal catalyzed reactions.

ACCOUNTS OF CHEMICAL RESEARCH (2021)

Article Chemistry, Multidisciplinary

Silaboration of [1.1.1]Propellane: A Storable Feedstock for Bicyclo[1.1.1]pentane Derivatives

Masaki Kondo et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Article Chemistry, Multidisciplinary

Catalytic Enantioselective Synthesis of anti-Vicinal Silylboronates by Conjunctive Cross-Coupling

Yan Meng et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Article Chemistry, Multidisciplinary

Transition-Metal-Free Cross-Coupling by Using Tertiary Benzylic Organoboronates

Mitsutaka Takeda et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Article Chemistry, Physical

DFT study of trialkylborohydride-catalysed hydrosilylation of alkenes - the mechanism and its implications

Mateusz Nowicki et al.

CATALYSIS SCIENCE & TECHNOLOGY (2020)

Review Chemistry, Multidisciplinary

Recent advances in metal-catalysed asymmetric sequential double hydrofunctionalization of alkynes

Zhaoyang Cheng et al.

CHEMICAL COMMUNICATIONS (2020)

Article Chemistry, Multidisciplinary

Nickel-Catalyzed Asymmetric Hydrogenation of N-Sulfonyl Imines

Bowen Li et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

Article Chemistry, Multidisciplinary

Highly Regioselective Sequential 1,1-Dihydrosilylation of Terminal Aliphatic Alkynes with Primary Silanes

Zhaoyang Cheng et al.

CHINESE JOURNAL OF CHEMISTRY (2019)

Article Chemistry, Multidisciplinary

Iron-Catalyzed Dihydrosilylation of Alkynes: Efficient Access to Geminal Bis(silanes)

Meng-Yang Hu et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

Review Chemistry, Inorganic & Nuclear

Recent advances in tridentate iron and cobalt complexes for alkene and alkyne hydrofunctionalizations

Huanan Wen et al.

COORDINATION CHEMISTRY REVIEWS (2019)

Article Chemistry, Multidisciplinary

The application of the chiral ligand DTBM-SegPHOS in asymmetric hydrogenation

Jianzhong Chen et al.

RESEARCH ON CHEMICAL INTERMEDIATES (2019)

Review Chemistry, Multidisciplinary

Hydride Transfer Reactions Catalyzed by Cobalt Complexes

Wenying Ai et al.

CHEMICAL REVIEWS (2019)

Review Chemistry, Multidisciplinary

Metal-catalyzed regiodivergent organic reactions

Carmen Najera et al.

CHEMICAL SOCIETY REVIEWS (2019)

Review Chemistry, Multidisciplinary

Earth-abundant transition metal catalysts for alkene hydrosilylation and hydroboration

Jennifer V. Obligacion et al.

NATURE REVIEWS CHEMISTRY (2018)

Review Chemistry, Multidisciplinary

Recent Advances in Hydrometallation of Alkenes and Alkynes via the First Row Transition Metal Catalysis

Jianhui Chen et al.

CHINESE JOURNAL OF CHEMISTRY (2018)

Article Multidisciplinary Sciences

Pd(OAc)(2)-catalyzed asymmetric hydrogenation of sterically hindered N-tosylimines

Jianzhong Chen et al.

NATURE COMMUNICATIONS (2018)

Article Chemistry, Multidisciplinary

Regiocontrol in the cobalt- catalyzed hydrosilylation of alkynes

Guojiao Wu et al.

CHEMICAL COMMUNICATIONS (2018)

Article Chemistry, Multidisciplinary

Regio- and Enantioselective Cobalt-Catalyzed Sequential Hydrosilylation/Hydrogenation of Terminal Alkynes

Jun Guo et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)

Article Chemistry, Multidisciplinary

Regiodivergent Catalysis: A Powerful Tool for Selective Catalysis

Nico Funken et al.

CHEMISTRY-A EUROPEAN JOURNAL (2017)

Article Chemistry, Multidisciplinary

Copper-Catalyzed Enantioselective Hydroboration of Unactivated 1,1-Disubstituted Alkenes

Won Jun Jang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

Article Chemistry, Multidisciplinary

Ligand-Substrate Dispersion Facilitates the Copper-Catalyzed Hydroamination of Unactivated Olefins

Gang Lu et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

Article Chemistry, Multidisciplinary

Highly Enantioselective Cobalt-Catalyzed Hydrosilylation of Alkenes

Biao Cheng et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

Article Chemistry, Multidisciplinary

C-O Functionalization of α-Oxyboronates: A Deoxygenative gem-Diborylation and gem-Silylborylation of Aldehydes and Ketones

Lu Wang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

Article Chemistry, Multidisciplinary

Cobalt-Catalyzed Asymmetric Sequential Hydroboration/Hydrogenation of Internal Alkynes

Jun Guo et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

Article Chemistry, Multidisciplinary

A Radical Cascade Enabling Collective Syntheses of Natural Products

Xiaobei Wang et al.

Article Chemistry, Multidisciplinary

Unexpected catalytic activity of simple triethylborohydrides in the hydrosilylation of alkenes

M. Zaranek et al.

CHEMICAL COMMUNICATIONS (2017)

Review Chemistry, Physical

Cobalt Complex-Catalyzed Hydrosilylation of Alkenes and Alkynes

Jian Sun et al.

ACS CATALYSIS (2016)

Article Chemistry, Multidisciplinary

Cobalt-Catalyzed Alkyne Hydrosilylation and Sequential Vinylsilane Hydroboration with Markovnikov Selectivity

Ziqing Zuo et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016)

Article Chemistry, Multidisciplinary

Highly Chemo-, Regio-, and Stereoselective Cobalt-Catalyzed Markovnikov Hydrosilylation of Alkynes

Jun Guo et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016)

Article Chemistry, Multidisciplinary

Pot economy and one-pot synthesis

Yujiro Hayashi

CHEMICAL SCIENCE (2016)

Article Chemistry, Multidisciplinary

London Dispersion in Molecular Chemistry-Reconsidering Steric Effects

J. Philipp Wagner et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2015)

Review Chemistry, Multidisciplinary

Catalytic bismetallative multicomponent coupling reactions: scope, applications, and mechanisms

Hee Yeon Cho et al.

CHEMICAL SOCIETY REVIEWS (2014)

Article Chemistry, Multidisciplinary

Cobalt-Catalyzed Enantioselective Hydroboration of 1,1-Disubstituted Aryl Alkenes

Lei Zhang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2014)

Article Chemistry, Multidisciplinary

Regio- and Stereoselective Hydrosilylation of Alkynes Catalyzed by Three-Coordinate Cobalt(I) Alkyl and Silyl Complexes

Zhenbo Mo et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2014)

Article Chemistry, Organic

Asymmetric cobalt catalysts for hydroboration of 1,1-disubstituted alkenes

Jianhui Chen et al.

ORGANIC CHEMISTRY FRONTIERS (2014)

Review Chemistry, Multidisciplinary

Activation of the Si-B Interelement Bond: Mechanism, Catalysis, and Synthesis

Martin Oestreich et al.

CHEMICAL REVIEWS (2013)

Review Chemistry, Multidisciplinary

Catalytic Selective Synthesis

Jessada Mahatthananchai et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2012)

Article Chemistry, Multidisciplinary

Potassium tert-butoxide-mediated regioselective silaboration of aromatic alkenes

Hajime Ito et al.

CHEMICAL COMMUNICATIONS (2012)

Article Chemistry, Organic

General and Practical One-Pot Synthesis of Dihydrobenzosiloles from Styrenes

Alexey Kuznetsov et al.

ORGANIC LETTERS (2012)

Editorial Material Chemistry, Multidisciplinary

One-Pot Reactions Accelerate the Synthesis of Active Pharmaceutical Ingredients

Carine Vaxelaire et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2011)

Review Chemistry, Multidisciplinary

Quantum Mechanical Investigations of Organocatalysis: Mechanisms, Reactivities, and Selectivities

Paul Ha-Yeon Cheong et al.

CHEMICAL REVIEWS (2011)

Review Chemistry, Multidisciplinary

Divergent reactions on racemic mixtures

Laura C. Miller et al.

CHEMICAL SOCIETY REVIEWS (2011)

Article Chemistry, Multidisciplinary

Silylboranes as New Tools in Organic Synthesis

Toshimichi Ohmura et al.

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN (2009)

Review Multidisciplinary Sciences

Polyborylated reagents for modern organic synthesis

Masaki Shimizu et al.

PROCEEDINGS OF THE JAPAN ACADEMY SERIES B-PHYSICAL AND BIOLOGICAL SCIENCES (2008)

Article Chemistry, Multidisciplinary

Catalytic enantioselective diboration, disilation and silaboration: new opportunities for asymmetric synthesis

Heather E. Burks et al.

CHEMICAL COMMUNICATIONS (2007)

Review Chemistry, Multidisciplinary

Element-element additions to unsaturated carbon-carbon bonds catalyzed by transition metal complexes

Irina Beletskaya et al.

CHEMICAL REVIEWS (2006)

Review Chemistry, Multidisciplinary

Catalytic Markovnikov and anti-Markovnikov functionalization of alkenes and alkynes: Recent developments and trends

M Beller et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2004)

Review Chemistry, Multidisciplinary

A planning strategy for diversity-oriented synthesis

MD Burke et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2004)

Review Multidisciplinary Sciences

Target-oriented and diversity-oriented organic synthesis in drug discovery

SL Schreiber

SCIENCE (2000)