Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 61, Issue 12, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.202107811
Keywords
electrophotocatalysis; hydrogen atom transfer; photoelectrochemistry; photoredox catalysis; preassembly
Categories
Funding
- Alexander von Humboldt Foundation
- Deutsche Bundestiftung Umwelt (DBU)
- Projekt DEAL
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Synthetic photoelectrochemistry (PEC) is a new frontier for the generation and handling of reactive intermediates, which allows selective single-electron transfer (SET) reactions in a greener way and expands the possibilities of redox transformations.
Synthetic photoelectrochemistry (PEC) is receiving increasing attention as a new frontier for the generation and handling of reactive intermediates. PEC permits selective single-electron transfer (SET) reactions in a much greener way and broadens the redox window of possible transformations. Herein, the most recent contributions are reviewed, demonstrating exciting new opportunities, namely, the combination of PEC with other reactivity paradigms (hydrogen-atom transfer, radical polar crossover, energy transfer sensitization), scalability up to multigram scale, novel selectivities in SET superoxidations/reductions and the importance of precomplexation to temporally enable excited radical ion catalysis.
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