Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 363, Issue 15, Pages 3616-3654Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.202100332
Keywords
Bamford-Stevens reaction; Catalysis; Cross-Coupling reactions; Diazo Compounds; Metal Carbenes; Tosylhydrazones
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Funding
- European Social Fund (ESF) [ESF/14-BM-A55-0004/18]
- Ministry of Education, Science and Culture of Mecklenburg-Vorpommern, Germany
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The review focuses on recent advancements in the field of transition-metal-catalyzed reactions of N-tosylhydrazones, highlighting the use of different transition metals as catalysts, synthetic applications, mechanistic studies, and applications in domino and multicomponent reactions.
Transition-metal-catalyzed reactions of N-tosylhydrazones provide a convenient access to various molecules by novel carbon-carbon or carbon-heteroatom bond formations via carbene-type intermediates. The present review highlights recent developments in the field emphasize of the employment of different transition metals as catalysts, synthetic applications, mechanistic studies and use in domino and multicomponent reactions.
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