Journal
ADVANCED MATERIALS
Volume 33, Issue 42, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.202101126
Keywords
dealloying; electrocatalysis; NiSb alloy; nitrogen reduction reaction
Categories
Funding
- NSFC [21925503, 51622102]
- MOST [2017YFA0206700]
- MOE [B12015]
- Fundamental Research Funds for the Central Universities
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The nanoporous NiSb alloy is reported as an efficient electrocatalyst for N-2 fixation, achieving high ammonia yield rate and Faradaic efficiency. Density functional theory calculations reveal the advantages of NiSb alloy in N-2 hydrogenation, providing a promising strategy for enhancing the reduction of inert molecules.
Ambient nitrogen reduction reaction (NRR) is attracting extensive interest but still suffers from sluggish kinetics owing to competitive rapid hydrogen evolution and difficult nitrogen activation. Herein, nanoporous NiSb alloy is reported as an efficient electrocatalyst for N-2 fixation, achieving a high ammonia yield rate of 56.9 mu g h(-1) mg(-1) with a Faradaic efficiency of 48.0%. Density functional theory calculations reveal that in NiSb alloy, Ni favors N-2 hydrogenation while the neighboring Sb separates active sites for proton and N-2 adsorption, which optimizes the adsorption/desorption of intermediates and enables an energetically favorable NRR pathway. This work indicates promising electrocatalytic application of the alloys of 3d and p block metals toward the NRR and provides an intriguing strategy to enhance the reduction of inert molecules by restraining the competitive hydrogen adsorption.
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