Journal
ADVANCED FUNCTIONAL MATERIALS
Volume 31, Issue 33, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adfm.202103311
Keywords
dynamic isomerization; liquid-crystalline networks; molecular motors; self-oscillation
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Funding
- National Key R&D Program of China [2018YFB0703704]
- National Natural Science Foundation of China [51903004, 51921002, 51927806, 51720105002]
- China Postdoctoral Science Foundation [2019M650299]
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This study introduces a novel overcrowded alkene motor that can achieve photoisomerization under UV exposure, and modulate the photodynamic storage modulus through dynamic stable-unstable isomerization. This leads to light-driven self-oscillating behavior from chaotic to regular movement in polymer networks.
The self-sustainable dynamic movement of soft actuators represents a continuous motion upon constant stimulus to achieve its great potential in emerging photoresponsive applications from self-propelling machines, artificial robots to advanced biomimetic devices. Conversion of dynamic isomerization of molecular motors and switches into macroscopic self-oscillation of soft materials is highly attractive but challenging. In this study, an overcrowded alkene motor with trifunctional acrylate groups is designed and synthesized, and its photoisomerization can be achieved in the liquid-crystalline networks. Furthermore, the photodynamic storage modulus can be mainly modulated by the dynamic stable-unstable isomerization of the molecular motor upon UV exposure. Thus, the light-driven self-oscillating behavior from chaotic to regular movement can be performed based on the photodynamic mechanical balance of the micro-oscillating modulus of the polymer network triggered by the dynamic reconfiguration of the motor. The results pave the way for inspirations in the development of advanced photoactive functional architectures and biomimetic actuators.
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