4.8 Article

Substrate-Independent Ti3C2Tx MXene Waterborne Paint for Terahertz Absorption and Shielding

Journal

ACS NANO
Volume 15, Issue 8, Pages 13646-13652

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsnano.1c04656

Keywords

MXene; terahertz EMI shielding; substrate-independent; waterborne paint; copolymer

Funding

  1. Science Challenge Project [TZ2018003]
  2. National Natural Science Foundation of China [61831012]
  3. Sichuan Province Science and Technology Support Program [2021JDTD0026]
  4. Outstanding Scholarship Foundation of UESTC [A1098531023601243]

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With the advancement of terahertz technology, there is a growing demand for materials that can shield or absorb electromagnetic interference. Recently, MXenes have gained interest for their high electron conductivity and hydrophilicity, with a copolymer-polyacrylic latex-based MXene waterborne paint showing strong THz EMI shielding efficiency.
With the development of terahertz (THz) technology, there is a booming demand of THz shielding/absorption materials to avoid electromagnetic interference (EMI) or pollution. Paints that can be fast solidified to form a film and stably adherent on arbitrary substrates are especially desired for the shielding/absorption applications. Recently, MXenes with high electron conductivity and hydrophilicity have attracted a great interest for EMI shielding. Here, we demonstrate a copolymer-polyacrylic latex (PAL) based MXene waterborne paint (MWP), which not only has strong THz EMI shielding/ absorption efficiency but also can easily adhere onto various substrates that are commonly used in the THz band. The viscosity of MWP can be tuned by adjusting the colloidal and viscous forces, and the cyano group in PAL provides a strong intermolecular polar interaction between MWP and the substrate. As a result, a 38.3-mu m-thick MWP on quartz exhibits EMI shielding value of 64.9 dB, and an excellent reflection-loss of 32.8 dB is obtained on MWP coated sponge foam. This substrate-independent MWP provides a simple and efficient way to achieving high-performance THz shielding/absorption.

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