4.8 Review

Graphene-Based Materials for Flexible Lithium-Sulfur Batteries

Journal

ACS NANO
Volume 15, Issue 9, Pages 13901-13923

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsnano.1c03183

Keywords

graphene-based materials; flexible lithium-sulfur batteries; sulfur cathodes; interlayers; lithium anodes; lithium polysulfides; freestanding structure; volumetric energy density; gravimetric energy density

Funding

  1. National Key Research and Development Program o f China [2019YFA0705700]
  2. National Natural Science Foundation of China [51774017, 51904016, 52072205]
  3. Key Program of Equipment Pre-Research Foundation of China [6140721020103]
  4. Tsinghua Shenzhen International Graduate School and Shenzhen Geim Graphene Center

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The increasing demand for wearable electronic devices has led to a growing interest in flexible batteries with high stability and desirable energy density. Graphene, known for its good conductivity and flexibility, has been used in various components of flexible lithium-sulfur batteries to improve their flexibility, energy density, and cycling stability.
The increasing demand for wearable electronic devices necessitates flexible batteries with high stability and desirable energy density. Flexible lithium-sulfur batteries (FLSBs) have been increasingly studied due to their high theoretical energy density through the multielectron chemistry of low-cost sulfur. However, the implementation of FLSBs is challenged by several obstacles, including their low practical energy density, short life, and poor flexibility. Various graphene-based materials have been applied to address these issues. Graphene, with good conductivity and flexibility, exhibits synergistic effects with other active/catalytic/flexible materials to form multifunctional graphene-based materials, which play a pivotal role in FLSBs. This review summarizes the recent progress of graphene-based materials that have been used as various FLSB components, including cathodes, interlayers, and anodes. Particular attention is focused on the precise nanostructures, graphene efficacy, interfacial effects, and battery layout for realizing FLSBs with good flexibility, energy density, and cycling stability.

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