Journal
ACS APPLIED MATERIALS & INTERFACES
Volume 13, Issue 36, Pages 42991-43001Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acsami.1c14862
Keywords
phase change materials; polyurethane; recyclability; self-healing; flame retardancy
Funding
- National Natural Science Foundation of China [51773129, 51903167]
- Sichuan Science and Technology Program [2019YFG0257]
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This study presents a novel PCM composite with superior recyclability, good self-healing capability, and excellent flame retardancy by utilizing TMCTP flame retardant and PEG for dynamic cross-linking on the polymeric skeleton. Introduction of TMCTP significantly enhances the self-healing efficiency, recyclability efficiency, and flame retardancy of the FPCMs, indicating their great potential for thermal energy storage applications.
Conventional polymeric phase change materials (PCMs) exhibit good shape stability, large energy storage density, and satisfactory chemical stability, but they cannot be recycled and self-healed due to their permanent cross-linking structure. Additionally, the high flammability of organic PCMs seriously restricts their applications for thermal energy storage (TES). Therefore, it is urgently required to explore PCM composites exhibiting superior recyclability, good self-healing capability, and excellent flame retardancy simultaneously. Herein, tri-maleimide end-capped cyclotriphosphazene flame retardant (TMCTP) was synthesized via the nucleophilic substitution between 1,3,5,2,4,6-triazatriphosphorine-2,2,4,4,6,6-hexachloride and N-(2-hydrox yethyl)-maleimide. Then, novel dynamically cross-linked PCM composites (FPCMs) with superior recyclability, good self-healing capability, and excellent flame retardancy were fabricated by bonding PEG and TMCTP to polymeric skeleton via reversible furan/ maleimide Diels-Alder (DA) reaction. TMCTP, which covalently and dynamically binding in the polymeric FPCMs, acted not only as an efficient flame retardant for reducing the flammability of PCM composites but also as dynamic cross-linking skeletons for thermally induced self-healing and recycling. Differential scanning calorimetry (DSC) analysis confirmed the reversible energy storage and release ability of FPCMs. Due to its reversible DA covalent bonds, the introduction of TMCTP endowed the FPCMs with considerably increased self-healing efficiency (up to 93.1%) and recyclability efficiency (94.6%). Moreover, with the introduction of TMCTP into FPCMs, the heat release rate (HRR) and total heat release (THR) significantly decreased, while the char residue and limiting oxygen index (LOI) value increased, confirming that the flame retardancy of FPCMs greatly improved. Hence, the synthesized FPCMs show enormous potential in TES applications.
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