Highly Efficient Water Splitting Catalyst Composed of N,P-Doped Porous Carbon Decorated with Surface P-Enriched Ni2P Nanoparticles

A non-noble-metal hybrid catalyst (Ni2P/NPC-P), composed of N,P-doped porous carbon decorated with surface P-enriched Ni2P nanoparticles, is developed to address the urgent challenges associated with mass production of clean hydrogen fuel. The synthesis features one-pot pyrolysis of inexpensive fluid catalytic cracking slurry, graphitic carbon nitride, and inorganic salts, followed by a feasible surface phosphidation process. As a non-noble metal catalyst, Ni2P/NPC-P demonstrates excellent performance in hydrogen evolution reaction in alkaline electrolytes with a low overpotential of 73 mV at a current density of 10 mA cm???2 (??10) and a small Tafel slope of 56 mV dec???1, meanwhile exhibits durability with no significant ??10 change after 2000 catalytic cycles. Theoretical calculation reveals that the negatively charged P-enriched surface accelerated the rate-determining transformation and desorption of OH*. In overall water splitting, the electrocatalyst achieves a low ??10 of 1.633 V, promising its potential in the cost-effective mass production of hydrogen fuel.

Automated summary

The non-noble metal hybrid catalyst Ni2P/NPC-P shows excellent performance in hydrogen evolution reaction with a low overpotential of 73 mV and a small Tafel slope of 56 mV dec^-1 in alkaline electrolytes, while maintaining durability with no significant change after 2000 catalytic cycles.