Efficient Nitrate-to-Ammonia Electroreduction at Cobalt Phosphide Nanoshuttles

The nitrate electroreduction reaction (NO3--ERR) is an efficient and green approach for nitrate remediation, which requires a highly active and selective electrocatalyst. In this work, porous and amorphous cobalt phosphide nanoshuttles (CoP PANSs) are successfully synthesized by using Mg2+ ion-doped calcium carbonate nanoshuttles (Mg-CaCO3 NSs) as the initial reaction precursor via precipitation transformation and a high-temperature phosphidation strategy. Various physical characterizations show that CoP PANSs have porous architecture, amorphous crystal structure, and big surface area. Electrochemical measurements reveal for the first time that CoP PANSs have outstanding electroactivity for NO3--ERR in a neutral electrolyte. At an applied potential of -0.5 V vs reversible hydrogen electrode, CoP PANSs can achieve a high Faraday efficiency (94.24 +/- 2.8%) and high yield rate (19.28 +/- 0.53 mg h(-1) mg(cat)(-1)) for ammonia production, which exceeds most reported values at various electrocatalysts for NO3--ERR. Thus, the present result indicates that cobalt phosphide nanomaterials have promising application for NO3--ERR.

Automated summary

This study successfully synthesized porous and amorphous cobalt phosphide nanoshuttles with outstanding electroactivity for nitrate electroreduction reaction. The CoP PANSs exhibited high Faraday efficiency and yield rate for ammonia production, surpassing most reported values for various electrocatalysts. This suggests promising applications for cobalt phosphide nanomaterials in nitrate remediation.