Journal
ACS APPLIED MATERIALS & INTERFACES
Volume 13, Issue 24, Pages 28908-28915Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acsami.1c06727
Keywords
boron; hydroxyl-terminated polybutadiene; solid fuel ramjet; mechanical property; combustion; energetic materials
Funding
- Office of Naval Research [N0001419-1-2085]
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The surface functionalization of boron particles with nonpolar oleoyl chloride significantly improves their dispersion and distribution within HTPB, leading to enhanced performance of composite materials.
High-speed air-breathing propulsion systems, such as solid fuel ramjets (SFRJ), are important for space exploration and national security. The development of SFRJ requires high-performance solid fuels with excellent mechanical and combustion properties. One of the current solid fuel candidates is composed of high-energy particles (e.g., boron (B)) and polymeric binder ( e.g., hydroxyl-terminated polybutadiene (HTPB)). However, the opposite polarities of the boron surface and HTPB lead to poor B particle dispersion and distribution within HTPB. Herein, we demonstrate that the surface functionalization of B particles with nonpolar oleoyl chloride greatly improves the dispersion and distribution of B particles within HTPB. The improved particle dispersion is quantitatively visualized through X-ray computed tomography imaging, and the particle/matrix interaction is evaluated by dynamic mechanical analysis. The surface-functionalized B particles can be uniformly dispersed up to 40 wt % in HTPB, the highest mass loading reported to date. The surface-functionalized B (40 wt %)/HTPB composite exhibits a 63.3% higher Young's modulus, 87.5% higher tensile strength, 16.2% higher toughness, and 16.8% higher heat of combustion than pristine B (40 wt %)/HTPB. The surface functionalization of B particles provides an effective strategy for improving the efficacy and safety of B/HTPB solid fuels for future high-speed air-breathing vehicles.
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