4.8 Article

Sandwich-Structured Photothermal Wood for Durable Moisture Harvesting and Pumping

Journal

ACS APPLIED MATERIALS & INTERFACES
Volume 13, Issue 28, Pages 33713-33721

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsami.1c08901

Keywords

moisture capture; sandwich structure; photothermal; wood; desiccant; dehumidification

Funding

  1. National Natural Science Foundation of China [51909291]
  2. Guangzhou Scientific and Technological Planning Project [202002030181]
  3. Fundamental Research Funds for the Central Universities [19lgzd17]
  4. U.S. Department of Energy, Office of Science, and Basic Energy Sciences

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Moisture capture combined with photothermal regeneration offers a sustainable approach to obtaining fresh water. The use of composite moisture absorbents based on hygroscopic salts is effective, but faces challenges such as desiccant leakage and salt accumulation on material surfaces. The development of a superhydrophobic-hydrophilic-hydrophobic photothermal wood embedded with CaCl2 addresses these issues and enables condensation and evaporation within the wood, making it a promising option for moisture harvesting and indoor dehumidification.
Moisture capture coupled with photothermal regeneration provides an alternative and sustainable way to acquire fresh water. Composite moisture absorbents based on hygroscopic salts are environmentally friendly, economically feasible, and of high efficiency but suffer from the unavoidable desiccant leakage during absorption and evaporation-induced salt accumulation on material surfaces during desorption. In this study, we develop a superhydrophobic-hydrophilic-hydrophobic photothermal wood embedded with CaCl2 to promote the durability of the absorbents. The sandwich structure serves as a liquid/vapor gate allowing vapor transport but forbidding liquid permeation, enabling the condensation and evaporation within the wood. Beyond moisture harvesting, the sandwich-structured photothermal wood exhibits potential in indoor dehumidification by pumping the moisture through an absorption-desorption cycle.

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