Combining Experiments and Theoretical Calculations to Investigate the Intercalation Behavior of Bis(trifluoromethanesulfonimide) Anion into Graphite Electrodes from Alkyl Phosphates

In dual-ion batteries (DIBs) utilizing organic electrolyte solutions, the combinations of electrolyte salt and solvent serve as a determiner of the electrochemical performance of graphite electrode partially because solvent participates in the anion intercalation procedure. In this case, every solvated-anion@graphite intercalation compound possesses the characteristic intercalated gallery height. However, in Li/graphite DIBs with concentrated LiTFSI (lithium bis(trifluoromethanesulfonimide))-alkyl phosphates (ca. trimethyl, triethyl, tripropyl, tributyl phosphate) solutions, solvated-TFSI @graphite intercalation compounds have the nearly identical intercalated gallery height of about 0.803 nm, which may be mainly attributed to both the big size of TFSI - anion and the rigid PO4 framework of these alkyl phosphate solvents.

Automated summary

The combination of electrolyte salt and solvent is crucial for the electrochemical performance of the graphite electrode in dual-ion batteries, with solvent participating in the anion intercalation process. In Li/graphite DIBs with concentrated LiTFSI-alkyl phosphates solutions, the nearly identical intercalated gallery height is mainly attributed to the size of the TFSI anion and the rigid PO4 framework of the alkyl phosphate solvents.