4.7 Article

Sputtered LiNi0.5Mn1.5O4 Thin Films for Lithium-Ion Microbatteries

Journal

ACS APPLIED ENERGY MATERIALS
Volume 4, Issue 4, Pages 3101-3109

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsaem.0c02831

Keywords

LiNi0.5Mn1.5O4; Li-ion microbatteries; thin lms; sputtered films; surface capacities; faradic process

Funding

  1. CASSIOPES project [ANR-17-CE09-0016-01]
  2. French network on electrochemical energy storage (RS2E)
  3. STORE-EX Labex
  4. Chevreul Institute [FR 2638]
  5. Ministere de l'Enseignement Superieur et de la Recherche
  6. Region Hauts de France
  7. FEDER

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This paper presents a detailed study on the influence of sputtering deposition parameters on the electrochemical properties of electrodes for lithium-ion microbatteries. The research aims to optimize the performance and investigate the relationship between structure and electrochemical properties.
To power miniaturized and smart electronic devices, lithium-ion microbatteries with high energy densities remain the most attractive solution. The Ni-substituted LiMn2O4, spinet material seems to be the most promising high-performance electrodes to significantly enhance the energy density of Li-ion microbatteries. Sputtered LiNi0.5Mn1.5O4 (LNMO) films deposited on a metallic current collector are known to deliver high capacity values with high rate capabilities. In this paper, we propose a detailed study on the influence of sputtering deposition parameters (gas flow rate and bias voltage) to optimize the electrochemical properties of the electrodes and to carefully investigate the structure-electrochemical property relationship.

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